1911 Encyclopædia Britannica/Electrokinetics
ELECTROKINETICS, that part of electrical science which is concerned with the properties of electric currents.
Classification of Electric Currents.—Electric currents are classified into (a) conduction currents, (b) convection currents, (c) displacement or dielectric currents. In the case of conduction currents electricity flows or moves through a stationary material body called the conductor. In convection currents electricity is carried from place to place with and on moving material bodies or particles. In dielectric currents there is no continued movement of electricity, but merely alimited displacement through or in the mass of an insulator or dielectric. The path in which an electric current exists is called an electric circuit, and may consist wholly of a conducting body, or partly of a conductor and insulator or dielectric, or wholly of a dielectric. In cases in which the three classes of currents are present together the true current is the sum of each separately. In the case of conduction currents the circuit consists of a conductor immersed in a non-conductor, and may take the form of a thin wire or cylinder, a sheet, surface or solid. Electric conduction currents may take place in space of one, two or three dimensions, but for the most part the circuits we have to consider consist of thin cylindrical wires or tubes of conducting material surrounded with an insulator; hence the case which generally presents itself is that of electric flow in space of one dimension. Self-closed electric currents taking place in a sheet of conductor are called "eddy currents."
Although in ordinary language the current is said to flow in the conductor, yet according to modern views the real pathway of the energy transmitted is the surrounding dielectric, and the so-called conductor or wire merely guides the transmission of energy in a certain direction. The presence of an electric current is recognized by three qualities or powers: (1) by the production of a magnetic field, (2) in the case of conduction currents, by the production of heat in the conductor, and (3) if the conductor is an electrolyte and the current unidirectional, by the occurrence of chemical decomposition in it. An electric current may also be regarded as the result of a movement of electricity across each section of the circuit, and is then measured by the quantity conveyed per unit of time. Hence if is the quantity of electricity which flows across any section of the conductor in the element of time the current
Electric currents may be also classified as constant or variable and as unidirectional or "direct," that is flowing always in the same direction, or "alternating," that is reversing their direction at regular intervals. In the last case the variation of current may follow any particular law. It is called a "periodic current" if the cycle of current values is repeated during a certain time called the periodic time, during which the current reaches a certain maximum value, first in one direction and then in the opposite, and in the intervals between has a zero value at certain instants. The frequency of the periodic current is the number of periods or cycles in one second, and alternating currents are described as low frequency or high frequency, in the latter case having some thousands of periods per second. A periodic current may be represented either by a wave diagram, or by a polar diagram. In the first case we take a straight line to represent the uniform flow of time, and at small equidistant intervals set up perpendiculars above or below the time axis, representing to scale the current at that instant in one direction or the other; the extremities of these ordinates then define a wavy curve which is called the wave form of the current (fig. 1). It is obvious that this curve can only be a single valued curve. In one particular and important case the form of the current curve is a simple harmonic curve or simple sine curve. If represents the periodic time in which the cycle of current values takes
|Fig. 1||Fig. 2|
place, whilst is the frequency or number of periods per second and stands for and is the value of the current at any instant and its maximum value, then in this case we have Such a current is called a "sine current" or simple periodic current.
In a polar diagram (fig. 2) a number of radial lines are drawn from a point at small equiangular intervals, and on these lines are set off lengths proportional to the current value of a periodic current at corresponding intervals during one complete period represented by four right angles (The extremities of these radii delineate a polar curve. The polar form of a simple sine current is obviously a circle drawn through the origin. As a consequence of Fourier's theorem it follows that any periodic curve having any wave form can be imitated by the superposition of simple sine currents differing in maximum value and in phase.
Definitions of Unit Electric Current.—In electrokinetic investigations we are most commonly limited to the cases of unidirectional continuous and constant currents (C.C. or D.C.), or of simple periodic currents, or alternating currents of sine form (A.C.). A continuous electric current is measured either by the magnetic effect it produces at some point outside its circuit, or by the amount of electrochemical decomposition it can perform in a given time on a selected standard electrolyte. Limiting our consideration to the case of linear currents or currents flowing in thin cylindrical wires, a definition may be given in the first place of the unit electric current in the centimetre, gramme, second (C.G.S.) of electromagnetic measurement (see Units, Physical). H. C. Oersted discovered in 1820 that a straight wire conveying an electric current is surrounded by a magnetic field the lines of which are self-closed lines embracing the electric circuit (see Electricity and Electromagnetism). The unit current in the electromagnetic system of measurement is defined as the current which, flowing in a thin wire bent into the form of a circle of one centimetre in radius, creates a magnetic field having a strength of units at the centre of the circle, and therefore would exert a mechanical force of dynes on a unit magnetic pole placed at that point (see Magnetism). Since the length of the circumference of the circle of unit radius is units, this is equivalent to stating that the unit current on the electromagnetic C.G.S. system is a current such that length acts on unit magnetic pole with a unit force at a unit of distance. Another definition, called the electrostatic of current, is as follows: Let any conductor be charged electricity and discharged through a thin wire at such a that one electrostatic unit of quantity (see Electrostatics) flows past any section of the wire in one unit of time. The electromagnetic unit of current defined as above is 3 X 1010 times larger than the electrostatic unit.
In the selection of a practical unit of current it was considered that the electromagnetic unit was too large for most purposes, whilst the electrostatic unit was too small; hence a practical unit of current called 1 ampere was selected, intended originally to be 1/10 of the absolute electromagnetic C.G.S. unit of current as above delined. The practical unit of current, called the international ampere, is, however, legally defined at the present time as the continuous unidirectional current which when flowing through a neutral solution of silver nitrate deposits in one second on the cathode or negative pole O.001118 of a gramme of silver. There is reason to believe that the international unit is smaller by about one part in a thousand, or perhaps by one part in 800, than the theoretical ampere defined as 1/10 part of the absolute electromagnetic unit. A periodic or alternating current is said to have a value of 1 ampere if when passed through a fine wire it produces in the same time the same heat as a unidirectional continuous current of 1 ampere as above electrochemically defined. In the case of a simple periodic alternating current having a simple sine wave form, the maximum value is equal to that of the equiheating continuous current multiplied by This equiheating continuous current is called the effective or root-mean-square (R.M.S.) value of the alternating one.
Resistance.—A current iiows in a circuit in virtue of an electromotive force (E.M.F.), and the numerical relation between the current and E.M.F. is determined by three qualities of the circuit called respectively, its resistance (R), inductance (L), and capacity (C). If we limit our consideration to the case of continuous unidirectional conduction currents, then the relation between current and E.M.F. is defined by Ohm's law, which states that the numerical value of the current is obtained as the quotient of the electromotive force by a certain constant of the circuit called its resistance, which is a function of the geometrical form of the circuit, of its nature, i.e. material, and of its temperature, but is independent of the electromotive force or current. The resistance (R) is measured in units called ohms and the electromotive force in volts (V), hence for a continuous current the value of the current in amperes (A) is obtained as the quotient of the electromotive force acting in the circuit reckoned in volts by the resistance in ohms, or Ohm established his law by a course of reasoning which was similar to that on which J. B. J. Fourier based his investigations on the uniform motion of heat in a conductor. As a matter of fact, however, Ohm's law merely states the direct proportionality of steady current to steady electromotive force in a circuit, and asserts that this ratio is governed by the numerical value of a quality of the conductor, called its resistance, which is independent of the current, provided that a correction is made for the change of temperature produced by the current. Our belief, however, in its universality and accuracy rests upon the close agreement between deductions made from it and observational results, and although it is not derivable from any more fundamental principle, it is yet one of the most certainly ascertained laws of electrokinetics.
Ohm's law not only applies to the circuit as a whole but to any part of it, and provided the part selected does not contain a source of electromotive force it may be expressed as follows:— The difference of potential (P.D.) between any two points of a circuit including a resistance but not including any source of electromotive force, is proportional to the product of the resistance and the current in the element, provided the conductor remains at the same temperature and the current is constant and unidirectional. If the current is varying we have, however, to take into account the electromotive force (E.M.F.) produced by this variation, and the product is then equal to the difference between the observed P.D. and induced E.M.F.
We may otherwise define the resistance of a circuit by saying that it is that physical quality of it in virtue of which energy is dissipated as heat in the circuit when a current fiows through it. The power communicated to any electric circuit when a current is created in it by a continuous unidirectional electromotive force is equal to and the energy dissipated as heat in that circuit by the conductor in a small interval of time is measured by Since by Ohm's law where is the resistance of the circuit, it follows that the energy dissipated as heat per unit of time in any circuit is numerically represented by and therefore the resistance is measured by the heat produced per unit of current, provided the current is unvarying.
Inductance.—As soon as we turn our attention, however, to alternating or periodic currents we find ourselves compelled to take into account another quality of the circuit, called its "inductance." This may be defined as that quality in virtue of which energy is stored up in connexion with the circuit in a magnetic form. It can be experimentally shown that a current cannot be created instantaneously in a circuit by any finite electromotive force, and that when once created it cannot be annihilated instantaneously. The circuit possesses a quality analogous to the inertia of matter. If a current is flowing in a circuit at any moment, the energy stored up in connexion with the circuit is measured by where the inductance of the circuit, is related to the current in the same manner as the quantity called the mass of a body is related to its velocity in the expression for the ordinary kinetic energy, viz. The rate at which this conserved energy varies with the current is called the "electrokinetic momentum" of this circuit (). Physically interpreted this quantity signifies the number of lines of magnetic flux due to the current itself which are self-linked with its own circuit.
Magnetic Force and Electric Currents.—In the case of every circuit conveying a current there is a certain magnetic force (see Magnetism) at external points which can in some instances be calculated. Laplace proved that the magnetic force due to an element of length of a circuit conveying a current at a point at a distance from the element is expressed by where is the angle between the direction of the current element and that drawn between the element and the point. This force is in a direction perpendicular to the radius vector and to the plane containing it and the element of current. Hence the determination of the magnetic force due to any circuit is reduced to a summation of the effects due to all the elements of length. For instance, the magnetic force at the centre of a circular circuit of radius carrying a steady current is since all elements are at the same distance from the centre. In the same manner, if we take a point in a line at right angles to the plane of the circle through its centre and at a distance the magnetic force along this line is expressed by Another important case is that of an infinitely long straight current. By summing up the magnetic force due to each element at any point outside the continuous straight current and at a distance from it, we can show that it is equal to or is inversely proportional to the distance of the point from the wire. In the above formula the current is measured in absolute electromagnetic units. If we reckon the current in amperes then
It is possible to make use of this last formula, coupled with an experimental fact, to prove that the magnetic force due to an element of current varies inversely as the square of the distance. If a flat circular disk is suspended so as to be free to rotate round a straight current which passes through its centre, and two bar magnets are placed on it with their axes in line with the current, it is found that the disk has no tendency to rotate round the current. This proves that the force on each magnetic pole is inversely as its distance from the current. But it can be shown that this law of action of the whole infinitely long straight current is a mathematical consequence of the fact that each element of the current exerts a magnetic force which varies inversely as the square of the distance. If the current flows times, round the circuit instead of once, we have to insert in place of in all the above formulae. The quantity is called the "ampere-turns" on the circuit, and it is seen that the magnetic field at any point outside a circuit is proportional to the ampere turns on it and to a function of its geometrical form and the distance of the point.
There is therefore a distribution of magnetic force in the field of every current-carrying conductor which can be delineated by lines of magnetic force and rendered visible to the eye by iron filings (see Magnetism). If a copper wire is passed vertically through a hole in a card on which iron filings are sprinkled, and a strong electric current is sent through the circuit, the filings arrange themselves in concentric circular lines making visible the paths of the lines of magnetic force (fig. 3). In the same manner, by passing a circular wire through a card and sending a strong current through the wire we can employ iron fllings to delineate for us the form of the lines of magnetic force (fig. 4).
|Fig. 3||Fig. 4|
In all cases a magnetic pole of strength placed in the field of an electric current, is urged along the lines of force with a mechanical force equal to where is the magnetic force. If then we carry a unit magnetic pole against the direction in which it would naturally move we do work. The lines of magnetic force embracing a current-carrying conductor are always loops or endless lines.
Thermal Effects of Currents.—J. P. Ioule proved that the heat produced by a constant current in a given time in a wire having a constant resistance is proportion alto the square of the strength of the current. This is known as Joule's law, and it follows, as already shown, as an immediate consequence of Ohm's law and the fact that the power dissipated electrically in a conductor, when an electromotive force is applied to its extremities, producing thereby a current in it, is equal to
|for copper wires|
|for iron wires|
|for platinoid wires.|
Action of one Current on Another.—The investigations of Ampère in connexion with electric currents are of fundamental importance in electrokinetics. Starting from the discovery of Oersted, Ampère made known the correlative fact that not only is there a mechanical action between a current and a magnet, but that two conductors conveying electric currents exert mechanical forces on each other. Ampére devised ingenious methods of making one portion of a circuit movable so that he might observe effects of attraction or repulsion between this circuit and some other fixed current. He employed for this purpose an astatic circuit B, consisting of a wire bent into a double rectangle round which a current flowed first in one and then in the opposite direction (fig. 5). In this way the circuit was removed from the action of the earth's magnetic, field, and yet one portion of it could, be submitted to the action of any other circuit C. The astatic circuit was pivoted by suspending it in mercury cups q, p, one of which was in electrical connexion with the tubular support A, and the other with a strong insulated wire passing up it.
Fig. 5. Ampère devised certain crucial experiments, and the theory deduced from them is based upon four facts and one assumption. He showed (1) that wire conveying a current bent back on itself produced no action upon a proximate portion of a movable astatic circuit; (2) that if the return Wire was bent zig-zag but close to the outgoing straight wire the circuit produced no action on the movable one, showing that the effect of an element of the circuit was proportional to its projected length; (3) that a closed circuit cannot cause motion in an element of another circuit free to move in the direction of its length; and (4) that the action of two circuits on one and the same movable circuit was null if one of the two fixed circuits was times greater than the other but times further removed from the movable circuit. From this last experiment by an ingenious line of reasoning he proved that the action of an element of current on another element of current varies inversely as a square of their distance. These experiments enabled him to construct a mathematical expression of the law of action between two elements of conductors conveying currents. They also enabled him to prove that an element of current may be resolved like a force into components in different directions, also that the force produced by any element of the circuit on an element of any other circuit was perpendicular to the line joining the elements and inversely as the square of their distance. Also he showed that this force was an attraction if the currents in the elements were in the same direction, but a repulsion if they were in opposite directions. From these experiments and deductions from them he built up a complete formula for the action of one element of a current of length
If and are the angles the elements make with the line joining them, and the angle they make with one another, then Ampère's expression for the mechanical force the elements exert on one another is
Ampère applied these with great mathematical skill to elucidate the mechanical actions of currents on each other, and experimentally confirmed the following deductions: (1) Currents in parallel circuits flowing in the same direction attract each other, but if in opposite directions repel each other. (2) Currents in wires meeting at an angle attract each other more into parallelism if both flow either to or from the angle, but repel each other more widely apart if they are in opposite directions. (3) A current in a small circular conductor exerts a magnetic force in its centre perpendicular to its plane and is in all respects equivalent to a magnetic shell or a thin circular disk of steel so magnetized that one face is a north pole and the other a south pole, the product of the area of the circuit and the current flowing in it determining the magnetic moment of the element. (4) A closely wound spiral current is equivalent as regards external magnetic force to a polar magnet, such a circuit being called a finite solenoid. (5) Two finite solenoid circuits act on each other like two polar magnets, exhibiting actions of attraction or repulsion between their ends.
Ampère's theory was wholly built up on the assumption of action at a distance between elements of conductors conveying the electric currents. Faraday's researches and the discovery of the fact-that the insulating medium is the real seat of the operations necessitates a change in the point of view from which we regard the facts discovered by Ampére. Maxwell showed that in any field of magnetic force there is a tension along the lines of force and a pressure at right angles to them; in other words, lines of magnetic force are like stretched elastic threads which tend to contract. If, therefore, two conductors lie parallel and have currents in them in the same direction they are impressed by a certain number of lines of magnetic force which pass round the two conductors, and it is the tendency of these to contract which draws the circuits together. If, however, the currents are in opposite directions then the lateral pressure of the similarly contracted lines of force between them pushes the conductors apart. Practical application of Ampère's discoveries was made by W. E. Weber in inventing the electrodynamometer, and later Lord Kelvin devised ampere balances for the measurement of electric currents based on the attraction between coils conveying electric currents.
Induction of Electric Currents.—Faraday in 1831 made the important discovery of the induction of electric currents (see Magnetism). If two conductors are placed parallel to each other, and a current in one of them, called the primary, started or stopped or changed in strength, every such alteration causes a transitory current to appear in the other circuit, called the secondary. This is due to the fact that as the primary current increases or decreases, its own embracing magnetic field alters, and lines of magnetic force are added to or subtracted from its fields. These lines do not appear instantly in their place at a distance, but are propagated out from the wire with a velocity equal to that of light; hence in their outward progress they cut through the secondary circuit, just as ripples made on the surface of water in a lake by throwing a stone on to it expand and cut through a stick held vertically in the water at a distance from the place of origin of the ripples. Faraday conhrmed this view of the phenomena by proving that the mere motion of a wire transversely to the lines of magnetic force of a permanent magnet gave rise to an induced electromotive force in the wire. He embraced all the facts in the single statement that if there be any circuit which by movement in a magnetic field, or by the creation or change in magnetic fields round it, experiences a change in the number of lines of force linked with it, then an electromotive force is set up in that circuit which is proportional at any instant to the rate at which the total magnetic fiux linked with it is changing. Hence if represents the total number of lines of magnetic force linked with a circuit of turns, then represents the electromotive force set up in that circuit. The operation of the induction coil (q.v.) and the transformer (q.v.) are based on this discovery. Faraday also found that if a copper disk A (fig. 6) is rotated between the poles
Fig. 6. of a magnet so that the disk moves with its plane perpendicular to the lines of magnetic force of the field, it has created in it an electromotive force directed from the centre to the edge or vice versa. The action of the dynamo (q.v.) depends on similar processes, viz. the cutting of the lines of magnetic force of a constant field produced by certain magnets by certain moving conductors called armature bars or coils in which an electromotive force is thereby created.
H. von Helmholtz, and later on Lord Kelvin, showed that the facts of induction of electric currents discovered by Faraday could have been predicted from the electrodynamic actions discovered by Ampère assuming the principle of the conservation of energy. Helmholtz takes the case of a circuit of resistance in which acts an electromotive force due to a battery or thermophile. Let a magnet be in the neighbourhood, and the potential of the magnet on the circuit be so that if a current existed in the circuit the work done on the magnet in the time is The source of electromotive force supplies in the time work equal to and according to Joule's law energy is dissipated equal to Hence, by the conservation of energy,
Oscillatory Currents.—In considering the motion of electricity in conductors we find interesting phenomena connected with the discharge of a condenser or Leyden jar (q.v.). This problem was first mathematically treated by Lord Kelvin in 1853 (Phil. Mag., 1853, 5, p. 292).
The above investigation shows that if we construct a circuit consisting of a condenser and inductance placed in series with one another, such circuit has a natural electrical time period of its own in which the electrical charge in it oscillates if disturbed. It may therefore be compared with a pendulum of any kind which when displaced oscillates with a time period depending on its inertia and on its restoring force.
The study of these electrical oscillations received a great impetus after H. R. Hertz showed that when taking place in electric circuits of a certain kind they create electromagnetic waves (see Electric Waves) in the dielectric surrounding the oscillator, and an additional interest was given to them by their application to telegraphy. If a Leyden jar and a circuit of low resistance but some inductance in series with it are connected across the secondary spark gap of an induction coil, then when the coil is set in action we have a series of bright noisy sparks, each of which consists of a train of oscillatory electric discharges from the jar. The condenser becomes charged as the secondary electromotive force of the coil is created at each break of the primary current, and when the potential difference of the condenser coatings reaches a certain value determined by the spark-ball distance a discharge happens. This discharge, however, is not a single movement of electricity in one direction but an oscillatory motion with gradually decreasing amplitude. If the oscillatory spark is photographed on a revolving plate or a rapidly moving film, we have evidence in the photograph that such a spark consists of numerous intermittent sparks gradually becoming feebler. As the coil continues to operate, these trains of electric discharges take place at regular intervals. We can cause a train of electric oscillations in one circuit to induce similar oscillations in a neighbouring circuit, and thus construct an oscillation transformer or high frequency induction coil.
Alternating Currents.—The study of alternating currents of electricity began to attract great attention towards the end of the 19th century by reason of their application in electrotechnics and especially to the transmission of power. A circuit in which a simple periodic alternating current flows is called a single phase circuit. The important difference between such a form of current flow and steady current flow arises from the fact that if the circuit has inductance then the periodic electric current in it is not in step with the terminal potential difference or electromotive force acting in the circuit, but the current lags behind the electromotive force by a certain fraction of the periodic time called the "phase difference." If two alternating currents having a fixed difference in phase flow in two connected separate but related circuits, the two are called a two-phase current. If three or more single-phase currents preserving a fixed difference of phase flow in various parts of a connected circuit, the whole taken together is called a poly phase current. Since an electric current is a vector quantity, that is, has direction as well as magnitude, it can most conveniently be represented by a line denoting its maximum value, and if the alternating current is a simple periodic current then the root-mean-square or effective value of the current is obtained by dividing the maximum value by Accordingly when we have an electric circuit or circuits in which there are simple periodic currents we can draw a vector diagram, the lines of which represent the relative magnitudes and phase differences of these currents.
Currents in Sheets.—In the case of current flow in plane sheets, we have to consider certain points called sources at which the current flows into the sheet, and certain points called sinks at which it leaves. We may investigate, first, the simple case of one source and one sink in an infinite plane sheet of thickness and conductivity Take any point in the plane at distances and from the source and sink respectively. The potential at is obviously given by
If we take a point half-way between the sink and the source as the origin of a system of rectangular co-ordinates, andif the distance between sink and source is equal to and the line joining them is taken as the axis of then the equation to the equipotential line is
Convection Currents.—The subject of convection electric currents has risen to great importance in connexion with modern electrical investigations. The question whether a statically electrified body in motion creates a magnetic field is of fundamental importance. Experiments to settle it were first undertaken in the year 1876 by H. A. Rowland, at a suggestion of H. von Helmholtz. After preliminary experiments, Rowland's first apparatus for testing this hypothesis was constructed, as follows:—An ebonite disk was covered with radial strips of goldleaf and placed between two other metal plates which acted as screens. The disk was then charged with electricity and set in rapid rotation. It.was found to affect a delicately suspended pair of astatic magnetic needles hung in proximity to the disk just as would, by Oersted's rule, a circular electric current coincident with the periphery of the disk. Hence the statically charged but rotating disk becomes in effect a circular electric current.
The experiments were repeated and confirmed by W. C. Röntgen (Wied. Ann., 1888, 35, p. 264; 1890, 40, p. 93) and by F. Himstedt (Wied. Ann., 1889, 38, p. 560). Later V. Crémieu again repeated them and obtained negative results (Com. rend., 1900, 130, p. 1544, and 131, pp. 578 and 797; 1901, 132, pp. 327 and 1108). They were again very carefully re conducted by H. Pender (Phil. Mag., 1901, 2, p. 179) and by E. P. Adams (id. ib., 285). Pender's work showed beyond any doubt that electric convection does produce a magnetic effect. Adams employed charged copper spheres rotating at a high speed in place of a disk, and was able to prove that the rotation of such spheres produced a magnetic field similar to that due to a circular current and agreeing numerically with the theoretical Value. It has been shown by J. J. Thomson (Phil. Mag., 1881, 2, p. 236) and O. Heaviside (Electrical Papers, vol. ii. p. 205) that an electrified sphere, moving with a velocity and carrying a quantity of electricity should produce a magnetic force at a point at a distance from the centre of the sphere, equal to where is the angle between the direction of and the motion of the sphere. Adams found the field produced by a known electric charge rotating at a known speed had a strength not, very different from that predetermined by the above formula. An observation recorded by R. W. Wood (Phil. Mag., 1902, 2, p. 659) provides a confirmatory fact. He noticed that if carbon-dioxide strongly compressed in asteel bottle is allowed to escape suddenly the cold produced solidifies some part of the gas, and the issuing jet is full of particles of carbon-dioxide snow. These by friction against the nozzle are electrified positively. Wood caused the jet of gas to pass through a glass tube 2–5 mm. in diameter, and found that these particles of electrified snow were blown through it with a Velocity of 2000 ft. a second. Moreover, he found that a magnetic needle hung near the tube was deflected as if held near an electric current. Hence the positively electrified particles in motion in the tube create a magnetic field round it.
Nature of an Electric Current.—The question, What is an electric current? is involved in the larger question of the nature of electricity. Modern investigations have shown that negative electricity is identical with the electrons or corpuscles which are components of the chemical atom (see Matter and Electricity). Certain lines of argument lead to the conclusion that a solid conductor is not only composed of chemical atoms, but that there is a certain proportion of free electrons present in it, the electronic density or number per unit of volume being determined by the material, its temperature and other physical conditions. If any cause operates to add or remove electrons at one point there is an immediate diffusion of electrons to re-establish equilibrium, and this electronic movement constitutes an electric current. This hypothesis explains the reason for the identity between the laws of diffusion of matter, of heat and of electricity. Electromotive force is then any cause making or tending to make an inequality of electronic density in conductors, and may arise from differences of temperature, i.e. thermoelectromotive force (see Thermoelectricity), or from chemical action when part of the circuit is an electrolytic conductor, or from the movement of lines of magnetic force across the conductor.
- See J. A. Fleming, The Alternate Current Transformer, vol. i. p. 519.
- See Maxwell, Electricity and Magnetism, vol. ii. chap. ii.
- See Maxwell, Electricity and Magnetism, vol. ii. 642.
- Experimental Researches, vol. i. ser. I.
- See Maxwell. Electricity and Magnetism, vol. ii. § 542, p. 178.
- See W.G. Rhodes, An Elementary Treatise on Alternating Currents (London, 1902), chap. vii.
- See J. A. Fleming, "Problems on the Distribution of Electric Currents in Networks of Conductors," Phil. Mag. (1885), or Proc. Phys. Soc. Lond. (1885), 7; also Maxwell, Electricity and Magnetism (2nd ed.), vol. i. p. 374, §280, 282b.
- See Berl. Acad. Ber., 1876, p. 211; also H. A. Rowland and C. T. Hutchinson, "On the Electromagnetic Effect of Convection Currents," Phil. Mag., 1889, 27, p. 445.