motive force E of the cell; so that in suitable units we have
.
A typical concentration-cell to which this formula may be applied may be constituted in the following way:—Let a quantity of zinc amalgam, in which the concentration of zinc is c1, be in contact with a dilute solution of zinc sulphate, and let this in turn be in contact with a quantity of zinc amalgam of concentration c2. When the two masses of amalgam are connected by a conducting wire outside the cell, an electric current flows in the wire from the weak to the strong amalgam,[1] while zinc cations pass through the solution from the strong amalgam to the weak. The electromotive force of such a cell, in which the current may be supposed to be carried solely by cations, is
Not content with the derivation of the electromotive force from considerations of energy, Nernst proceeded to supply a definite mechanical conception of the process of conduction in electrolytes. The ions are impelled by the electric force associated with the gradient of potential in the electrolyte. But this is not the only force which acts on them; for, since their available energy decreases as the concentration decreases, there must be a force assisting every process by which the concentration is decreased. The matter may be illustrated by the analogy of a gas compressed in a cylinder fitted with a piston; the available energy of the gas decreases as its degree of compression decreases; and therefore that movement of the piston which tends to decrease the compression is assisted by a force—the "pressure" of the gas on the piston. Similarly, if a solution were contained within a cylinder fitted with a piston which is permeable to the pure solvent but not to the solute, and if the whole were immersed in pure solvent, the available energy of
- ↑ It will hardly be necessary to remark that this supposed direction of the current is purely conventional.
2 C 2
