found, however, by M. P. E. Berthelot that under the influence of the silent electric discharge, a mixture of benzene vapour and argon underwent contraction, with formation of a gummy product from which the argon could be recovered.
The facts detailed in the original memoir led to the conclusion that argon was an element or a mixture of elements, but the question between these alternatives was left open. The behaviour on liquefaction, however, seemed to prove that in the latter case either the proportion of the subordinate constituents was small, or else that the various constituents were but little contrasted. An attempt, somewhat later, by Ramsay and J. Norman Collie to separate argon by diffusion into two parts, which should have different densities or refractivities, led to no distinct effect. More recently Ramsay and M. W. Travers have obtained evidence of the existence in the atmosphere of three new gases, besides helium, to which have been assigned the names of neon, krypton and xenon. These gases agree with argon in respect of the ratio of the specific heats and in being non-oxidizable under the electric spark. As originally defined, argon included small proportions of these gases, but it is now preferable to limit the name to the principal constituent and to regard the newer gases as “companions of argon.” The physical constants associated with the name will scarcely be changed, since the proportion of the “companions” is so small. Sir William Ramsay considers that probably the volume of all of them taken together does not exceed 1⁄400th part of that of the argon. The physical properties of these gases are given in the following table (Proc. Roy. Soc. lxvii. p. 331, 1900):—
|Refractivities (air = 1)
Densities (O = 16)
Boiling points at 760 mm.
Weight of 1 c.c. of liquid
c. 6° abs.
below 68° abs.
The glow obtained in vacuum tubes is highly characteristic, whether as seen directly or as analysed by the spectroscope.
Now that liquid air is available in many laboratories, it forms an advantageous starting-point in the preparation of argon. Being less volatile than nitrogen, argon accumulates relatively as liquid air evaporates. That the proportion of oxygen increases at the same time is little or no drawback. The following analyses (Rayleigh, Phil. Mag., June 1903) of the vapour arising from liquid air at various stages of the evaporation will give an idea of the course of events:—
|Argon as a Percentage|
of the Nitrogen and
ARGONAUTS (Άργοναῦται, the sailors of the “Argo”), in Greek legend a band of heroes who took part in the Argonautic expedition under the command of Jason, to fetch the golden fleece. This task had been imposed on Jason by his uncle Pelias (q.v.), who had usurped the throne of Iolcus in Thessaly, which rightfully belonged to Jason’s father Aeson. The story of the fleece was as follows. Jason’s uncle Athamas had two children, Phrixus and Helle, by his wife Nephele, the cloud goddess. But after a time he became enamoured of Ino, the daughter of Cadmus, and neglected Nephele, who disappeared in anger. Ino, who hated the children of Nephele, persuaded Athamas, by means of a false oracle, to offer Phrixus as a sacrifice, as the only means of alleviating a famine which she herself had caused by ordering the grain to be secretly roasted before it was sown. But before the sacrifice the shade of Nephele appeared to Phrixus, bringing a ram with a golden fleece on which he and his sister Helle endeavoured to escape over the sea. Helle fell off and was drowned in the strait, which after her was called the Hellespont. Phrixus, however, reached the other side in safety, and proceeding by land to Aea in Colchis on the farther shore of the Euxine Sea, sacrificed the ram, and hung up its fleece in the grove of Ares, where it was guarded by a sleepless dragon.
Jason, having undertaken the quest of the fleece, called upon the noblest heroes of Greece to take part in the expedition. According to the original story, the crew consisted of the chief members of Jason’s own race, the Minyae. But when the legend became common property, other and better-known heroes were added to their number—Orpheus, Castor and Polydeuces (Pollux), Zetes and Calaīs, the winged sons of Boreas, Meleager, Theseus, Heracles. The crew was supposed to consist of fifty, agreeing in number with the fifty oars of the “Argo,” so called from its builder Argos, the son of Phrixus, or from ἀργός (swift). It was a larger vessel than had ever been seen before, built of pine-wood that never rotted from Mount Pelion. The goddess Athena herself superintended its construction, and inserted in the prow a piece of oak from Dodona, which was endowed with the power of speaking and delivering oracles. The outward course of the “Argo” was the same as that of the Greek traders, whose settlements as early as the 6th century B.C. dotted the southern shores of the Euxine. The first landing-place was the island of Lemnos, which was occupied only by women, who had put to death their fathers, husbands and brothers. Here the Argonauts remained some months, until they were persuaded by Heracles to leave. It is known from Herodotus (iv. 145) that the Minyae had formed settlements at Lemnos at a very early date. Proceeding up the Hellespont, they sailed to the country of the Doliones, by whose king, Cyzicus, they were hospitably received. After their departure, being driven back to the same place by a storm, they were attacked by the Doliones, who did not recognize them, and in a battle which took place Cyzicus was killed by Jason. After Cyzicus had been duly mourned and buried, the Argonauts proceeded along the coast of Mysia, where occurred the incident of Heracles and Hylas (q.v.). On reaching the country of the Bebryces, they again landed to get water, and were challenged by the king, Amycus, to match him with a boxer. Polydeuces came forward, and in the end overpowered his adversary, and bound him to a tree, or according to others, slew him. At the entrance to the Euxine, at Salmydessus on the coast of Thrace, they met Phineus, the blind and aged king whose food was being constantly polluted by the Harpies. He knew the course to Colchis, and offered to tell it, if the Argonauts would free him from the Harpies. This was done by the winged sons of Boreas, and Phineus now told them their course, and that the way to pass through the Symplegades or Cyanean rocks—two cliffs which moved on their bases and crushed whatever sought to pass—was first to fly a pigeon through, and when the cliffs, having closed on the pigeon, began to retire to each side, to row the “Argo” swiftly through. His advice was successfully followed, and the “Argo” made the passage unscathed, except for trifling damage to the stern. From that time the rocks became fixed and never closed again. The next halting-places were the country of the Maryandini, where the helmsman Tiphys died, and the land of the Amazons on the banks of the Thermodon. At the island of Aretias they drove away the Stymphalian birds, who used their feathers of brass as arrows. Here they found and took on board the four sons of Phrixus who, after their father’s death, had been sent by Aeetes, king of Colchis, to fetch the treasures of Orchomenus, but had been driven by a storm upon the island. Passing near Mount Caucasus, they heard the groans of Prometheus and the flapping of the wings of the eagle which gnawed his liver. They now reached their goal, the river Phasis, and the following morning Jason repaired to the palace of Aeetes, and demanded
- Sir James Dewar, Compt. Rend. (1904), 139, 261 and 241.