interchange of temperature takes place. The smoke gases,
instead of escaping directly into the atmosphere, are made to
pass through one of these chambers, giving up part of their
heat to the brickwork. After a certain time the draught is
changed by means of valves, the smoke gases are passed through
another chamber, and the cold air intended to feed the combustion
is made to pass through the first chamber, where it
takes up heat from the white-hot bricks, and is thus heated up
to a bright red heat until the chamber is cooled down too far,
when the draughts are again reversed. Sometimes the producer
gas itself is heated up in this manner (especially when it has
been cooled down by travelling a long distance); in that case
four recuperator chambers must be provided instead of two.
Another class of recuperators is not founded on the alternating
system, but acts continuously; the smoke gases travel always
in the same direction in flues contiguous to other flues or pipes
in which the air flows in the opposite direction, an interchange
of heat taking place through the walls of the flues or pipes. Here
the surface of contact must be made very large if a good effect
is to be produced. In both cases not merely is a saving effected
of all the calories which are abstracted by the cold air from the
recuperator, but as less fuel has to be burned to get a given
effect, the quantity of smoke gas is reduced. For details and
other producer gases, see Gas, II. For Fuel and Power.
Gas-firing in the manner just described can be brought about by very simple means, viz. by lowering the fire-grate of an ordinary fire-place to at least 4 ft. below the fire-bridge, and by introducing the air partly below the grate and partly behind the fire-place, at or near the point where the greatest heat is required. Usually, however, more elaborate apparatus is employed, some of which we shall describe below. Gas-firing has now become universal in some of the most important industries and nearly so in others. The present extension of steel-making and other branches of metallurgy is intimately connected with this system, as is the modern method of glass-making, of heating coal gas retorts and so forth.
The composition of producer gas differs considerably, principally according to the material from which it is made. Analyses of ordinary producer gas (not such as falls under the heading of “semi-water gas,” see sub C) by volume show 22 to 33% CO, 1 to 7% CO2, 0.5 to 2% H2, 0.5 to 3% hydrocarbons, and 64 to 68% N2.
B. Water Gas.—The reaction of steam on highly heated carbonaceous matter was first observed by Felice Fontana in 1780. This was four years before Henry Cavendish isolated hydrogen from water, and thirteen years before William Murdoch made illuminating gas by the distillation of coal, so that it was no wonder that Fontana’s laboratory work was soon forgotten. Nor had the use of carburetted water gas, as introduced by Donovan in 1830 for illuminating purposes, more than a very short life. More important is the fact that during nine years the illumination of the town of Narbonne was carried on by incandescent platinum wire, heated by water gas, where also internally heated generators were for the first time regularly employed. The Narbonne process was abandoned in 1865, and for some time no real progress was made in this field in Europe. But in America, T. S. C. Lowe, Strong, Tessié du Motay and others took up the matter, the first permanent success being obtained by the introduction (1873) of Lowe’s system at Phoenixville, Pa. In the United States the abundance of anthracite, as well as of petroleum naphtha, adapted for carburetting the gas, secures a great commercial advantage to this kind of illuminant over coal gas, so that now three-fourths of all American gas-works employ carburetted water gas. In Europe the progress of this industry was naturally much less rapid, but here also since 1882, when the apparatus of Lowe and Dwight was introduced in the town of Essen, great improvements have been worked out, principally by E. Blass, and by these improvements water gas obtained a firm footing also for certain heating purposes. The American process for making carburetted water gas, as an auxiliary to ordinary coal gas, was first introduced by the London Gas Light and Coke Company on a large scale in 1890.
Water gas in its original state is called “blue gas,” because it burns with a blue, non-luminous flame, which produces a very high temperature. According to the equation C + H2O = CO + H2, this gas consists theoretically of equal volumes of carbon monoxide and hydrogen. We shall presently see why it is impossible to avoid the presence of a little carbon dioxide and other gases, but we shall for the moment treat of water gas as if it were composed according to the above equation. The reaction C + H2O = CO + H2 is endothermic, that is, its thermal value is negative. One gram-molecule of carbon produces 97 great calories (1 great calorie or kilogram-calorie = 1000 gram-calories) when burning to CO2, and this is of course the maximum effect obtainable from this source. If the same gram-molecule of carbon is used for making water gas, that is, CO + H2, the heat produced by the combustion of the product is 68.4 + 57.6 = 126 great calories, an apparent surplus of 29 calories, which cannot be got out of nothing. This is made evident by another consideration. In the above reaction C is not burned to CO2, but to CO, a reaction which produces 28.6 calories per gram-molecule. But as the oxygen is furnished from water, which must first be decomposed by the expenditure of energy, we must introduce this amount, 68.5 calories in the case of liquid water, or 57.6 calories in the case of steam, as a negative quantity, and the difference, viz. + 28.6 − 57.6 = 29 great calories, represents the amount of heat to be expended from another source in order to bring about the reaction of one gram-molecule of carbon on one gram-molecule of H2O in the shape of steam. This explains why steam directed upon incandescent coal will produce water gas only for a very short time: even a large mass of coal will quickly be cooled down so much that at first a gas of different composition is formed and soon the process will cease altogether. We can avoid this result by carrying on the process in a retort heated from without by an ordinary coal fire, and all the early water gas apparatus was constructed in this way; but such a method is very uneconomical, and was long ago replaced by a process first patented by J. and T. N. Kirkham in 1854, and very much improved by successive inventors. This process consists in conducting the operation in an upright brick shaft, charged with anthracite, coke or other suitable fuel. This shaft resembles an ordinary gas producer, but it differs in being worked, not in a continuous manner, which, as shown above, would be impossible, but by alternately blowing air and steam through the coal for periods of a few minutes each. During the first phase, when carbon is burned by atmospheric oxygen, and thereby heat is produced, this heat, or rather that part of it which is not carried away by radiation and by the products of combustion on leaving the apparatus, is employed in raising the temperature of the remaining mass of fuel, and is thus available for the second phase, in which the reaction (b) C + H2O = CO + H2 goes on with the abstraction of a corresponding amount of heat from the incandescent fuel, so that the latter rapidly cools down, and the process must be reversed by blowing in air and so forth. The formation of exactly equal volumes of carbon monoxide and hydrogen goes on only at temperatures over 1200° C., that is, for a very few minutes. Even at 1100° C. a little CO2 can be proved to exist in the gas, and at 900° its proportion becomes too high to allow the process to go on. About 650° C. the CO has fallen to a minimum, and the reaction is now essentially (c) C + 2H2O = CO2 + 2H2; soon after the temperature of the mass will have fallen to such a low point that the steam passes through it without any perceptible action. The gas produced by reaction (c) contains only two-thirds of combustible matter, and is on that account less valuable than proper water gas formed by reaction (b); moreover, it requires the generation of twice the amount of steam, and its presence is all the less desirable since it must soon lead to a total cessation of the process. In ordinary circumstances it is evident that the more steam is blown in during a unit of time, the sooner reaction (c) will set in; on the other hand, the more heat has been accumulated in the producer the longer can the blowing-in of steam be continued.
The process of making water gas consequently comprises
