Polonium from the analytical point of view, is analogous to bismuth, and separates out with the latter. By one of the following methods of fractionating, bismuth products are obtained mcreasingly rich in polonium: —
1. Sublimation of the sulphides in vacuo; the active sulphide is much more volatile than bismuth sulphide.
2. Precipitation of solutions of the nitrate by water; the precipitate of the basic nitrate is much more active than the salt which remains in solution.
3. Precipitation by sulphuretted hydrogen of a hydrochloric acid solution, strongly acid; the precipitated sulphides are considerably more active than the salt which remains in solution.
Radium is a substance which accompanies the barium obtained from pitchblende; it resembles barium in its reactions, and is separated from it by difference of solubility of the chlorides in water, in dilute alcohol, or in water acidified with hydrochloric acid. We effect the separation of the chlorides of barium and radium by subjecting the mixture to fractional crystallisation, radium chloride being less soluble than that of barium.
A third strongly radio-active body has been identified in pitchblende by M. Debierne, who gave it the name of actinium. Actinium accompanies certain members of the iron group contained in pitchblende; it appears in particular allied to thorium, from which it has not yet been found possible to separate it. The extraction of actinium from pitchblende is a very difficult operation, the separations being as a rule incomplete.
All three of the new radio-active bodies occur in quite infinitesimal amount in pitchblende. In order to obtain them in a more concentrated condition, we were obliged to treat several tons of residue of the ore of uranium. The rough treatment was carried out in the factory; and this was followed by processes of purification and concentration. We thus succeeded in extracting from thousands of kilogrms. of crude material a few decigrammes of products which were exceedingly active as compared with the ore from which they were obtained. It is obvious that this process is long, arduous, and costly.
Other new radio-active bodies have been notified since the termination of our work. M. Giesel, on the one hand, and MM. Hoffmann and Strauss on the other, have announced the probable existence of a radio-active body similar to lead in its chemical properties. At present only a few samples of this substance have been obtained.
