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62
mdme. curie's thesis:

the radiation of the radio-active bodies is to be investigated by the fluoroscopic method. The effect of the radium rays may be followed at distances greater than 2 m. Phosphorescent zinc sulphide is made extremely luminous, but this body has the inconvenient property of preserving its luminosity for some time after the action of the rays has ceased.

The fluorescence produced by radium may be observed when the fluorescent screen is separated from the radium by absorbent screens. We were able to observe the illumination of a screen of barium platinocyanide across the human body. However, the action is incomparably greater when the screen is placed immediately in contact with the radium, being separated from it by no solid screen at all. All the groups of rays appear capable of producing fluorescence.

In order to observe the action of polonium, the substance must be placed close to the fluorescent screen, without the intervention of a solid screen, unless the latter be extremely thin.

The luminosity of fluorescent substances exposed to the action of radio-active bodies diminishes with time. At the same time the fluorescent substance undergoes a transformation. The following are examples:—

Radium rays transform barium platinocyanide into a brown, less luminous variety (an action similar to that produced by Röntgen rays, and described by M. Villard). Uranium sulphate and potassium sulphate are similarly altered. The changed barium platinocyanide is partially regenerated by the action of light. If the radium be placed beneath a layer of barium platinocyanide spread on paper, the platinocyanide becomes luminous; if the system be kept in the dark, the platinocyanide becomes changed, and its luminosity diminishes considerably. But if the whole be exposed to light, the platinocyanide is partially regenerated, and if the whole is replaced in darkness the luminosity reappears with vigour. By means of a fluorescent body and a radio-active body, we have therefore obtained a system which acts as a phosphorescent body capable of long duration of phosphorescence.

Glass made fluorescent by the action of radium becomes coloured brown or violet. At the same time its fluorescence diminishes. If the glass thus changed be warmed, it is decolorised, and when this occurs the glass becomes luminous. The glass has now regained its fluorescent property in the same degree as before the transformation.