two ratios are practically equal to one another, and are equivalent to 1·45.
A specimen of radium-barium chloride which, after having been prepared in the solid state, has attained a limiting activity of 62, is maintained in a state of fusion for some hours; the fused product is then powdered. The product regains a new limiting activity equal to 140, which is twice as great as that to which it was able to attain when prepared in the solid state without having been sensibly heated during evaporation.
I have investigated the law of increase of activity of radium compounds after heating. The following are the results of two series of determinations:—The figures of Table I. and II. represent the intensity of the radiation (I) as a function of time, the limiting intensity being supposed equal to 100, and the time being reckoned from the close of the heating. Table I. (Fig. 13, Curve I.) refers to the total radiation of a specimen of barium-radium chloride. Table II. (Fig. 13, Curve II.) relates to the penetrating radiation of a specimen of barium-radium sulphate, the intensity of the radiation which traversed 3 cm. of air and 0·01 m.m. of aluminium having been determined. The two products were subjected to a bright red heat for seven hours.
| Table I. | | Table II. | ||||
| Time. Days. |
| I. | Time. Days. |
| I. | |
| 0 | 16·2 | 0 | 0·8 | |||
| 0·6 | 25·4 | 0·7 | 13 | |||
| 1 | 27·4 | 1 | 18 | |||
| 2 | 38 | 1·9 | 26·4 | |||
| 3 | 46·3 | 6 | 46·2 | |||
| 4 | 54 | 10 | 55·5 | |||
| 6 | 67.5 | 14 | 64 | |||
| 10 | 84 | 18 | 71·8 | |||
| 24 | 95 | 27 | 81 | |||
| 57 | 100 | 36 | 91 | |||
| 50 | 95·5 | |||||
| 57 | 99 | |||||
| 84 | 100 | |||||
I made several other series of determinations, but the results did not agree well.
The effect of heating does not persist when the heated radium compound is dissolved. Of two specimens of the same radium compound of activity 1800, one was strongly heated and its activity thereby reduced to 670. The two portions being now dissolved and left in solution for twenty
