obtained by treating the mono chloride with chlorine under water;
evaporation in a vacuum gives colourless deliquescent crystals of
TlCl3·H2O. By heating the metal or thallous chloride in chlorine,
TlCl·TlCl3 is obtained, which on further heating gives 3TlCl·TlCl3.
as a yellowish brown mass. The chloride when anhydrous is a
crystalline mass which melts at 24°. It forms several double salts,
e.g. with hydrochloric acid and the alkaline chlorides, and also
with nitrosyl chloride. The chlorine is not completely precipitated
by silver nitrate in nitric acid solution, the ionization apparently
not proceeding to all the chlorine atoms. Thallic iodide, TlI3, is
interesting on account of its isomorphism with rubidium and
caesium tri-iodides, a resemblance which suggests the formula
TlI(I2) for the salt, in which the metal is obviously monovalent.
On the halogen compounds see V. Thomas, Abst. J.C.S. (1907),
ii. 547. Thallic sulphate, Tl2(SO4)3·7H2O, and thallic nitrate,
Tl(NO3)3·8H2O, are obtained as colourless crystals on the evaporation
of a solution of the oxide in the corresponding acid. The
sulphate decomposes into sulphuric acid and the trioxide on warming
with water, and differs from aluminium sulphate in not forming
alums.
Analysis.—All thallium compounds volatile or liable to dissociation at the temperature of the flame of a Bunsen lamp impart to such flame an intense green colour. The spectrum contains a bright green of wave-length 5351. From solutions containing it as thallous salt the metal is easily precipitated as chloride, iodide, or chloroplatinate by the corresponding reagents. Sulphuretted hydrogen, in the presence of free mineral acid, gives no precipitate; sulphide of ammonium, from neutral solutions, precipitates Tl2S as a dark brown or black precipitate, insoluble in excess of reagent. Thallic salts are easily reduced to thallous by means of solution of sulphurous acid, and thus rendered amenable to the above reactions. The chloroplatinate serves for the quantitative estimation. L. F. Hawley employs sodium thiostannate which precipitates thallium as Tl2SnS4, insoluble in water, and which may be dried on a Gooch filter at 105°. It may be noted that all thallium compounds are poisonous.
The atomic weight of thallium was determined very carefully by Crookes, who found Tl＝204·2 (O＝16); this figure was confirmed by Lepierre in 1893.
THALWEG (a German word compounded from Thal, valley,
and Weg, way) in physical geography, a term adopted into
English usage signifying the line of greatest slope along the
bottom of a valley, i.e. a line drawn through the lowest points
of a valley in its downward slope. It thus marks the natural
direction of a watercourse.
THAMES, the chief river of England, rising in several small
streams among the Cotteswold Hills in Gloucestershire. Its
source is generally held to be at a place known as Thames Head,
in the parish of Coates, 3 m. W. by S. of Cirencester; but claims
have also been advanced on behalf of the Seven Springs, the
head waters of the river Churn, 5 m. S. of Cheltenham. The
length of the river from Thames Head Bridge to London Bridge
is 16114 m. and from London Bridge to the Note, 4734 m., a total
of 209 m. The width at Oxford is about 150 ft., at Teddington
250 ft., at London Bridge 750 ft., at Gravesend 2100 ft., and
between Sheerness and Shoeburyness, immediately above the
Nore, 512 m. The height of Thames Head above sea-level is
356 ft., but that of Seven Springs, the adoption of which as
the source would extend the length of the river by several miles,
is 700 ft. The height of the river at Lechlade is 237 ft., the
average fall between Lechlade and London, 14314 m., being
rather less than 20 in. per mile. The drainage area of the Thames
is 5024 sq. m., including that of the Medway, which, as it joins
the estuary immediately above Sheerness, may be considered
a tributary of the Thames. The Thames forms part of the
Gloucestershire-Wiltshire boundary to a point below Lechlade;
thence for a short distance it separates Gloucestershire from
Berkshire; after which it separates successively Oxfordshire
and Berkshire, Buckinghamshire and Berkshire, Middlesex and
Surrey, and finally, at its estuary, Essex and Kent. In the
succeeding paragraph the bracketed figures indicate the distance
in miles above London Bridge.
The upper course lies through a broad valley, between the foot-hills of the Cotteswolds on the north, and the slight elevations dividing it from the Vale of White Horse on the south. The scenery is rural and pleasant; the course of the river winding. Before reaching Oxford the stream swings north, east and south to encircle the wooded hills of Wytham and Cumnor, which overlook the city from the west. The Windrush joins from the north (left) at New Bridge (12634), the Evenlode near Eynsham (119), and the Cherwell at Oxford (112). Between Lechlade and Oxford the main channel sends off many narrow branches; the waters of the Windrush are similarly distributed, and the branches in the neighbourhood of Oxford form the picturesque “ backwaters ” which only light pleasure boats can penetrate. The river then follows a valley confined between the hills on either side of Oxford, passes the pleasant woods of Nuneham, and at Abingdon (10312) receives the Ock from the Vale of White Horse. At Dorchester (9514) the Thame enters on the left, and the river then passes Wallingford (9034) and Goring (85). Hitherto from Oxford its course, though greatly winding, has lain generally in a southerly direction, but it now bends eastward, and breaches the chalk hills in a narrow gap, dividing the Chilterns from the downs of Berkshire or White Horse Hills. From this point as far as Taplow the southern slopes of the Chilterns descend more or less closely upon the river; they are finely Wooded, and the scenery is peculiarly beautiful, especially in early summer. The charm of the Thames is indeed maintained throughout its course; the view of the rich valley from Richmond Hill, of the outskirts of London, is celebrated; the river is practically the only physical attribute to the beauty of the metropolis itself, and the estuary, with its burden of shipping and its industrial activity, is no less admirable. At Pangbourne (8034) the Thames receives the Pang on the right, and at Reading (7412) the Kennet on the same side. After passing Reading it bends northward to Henley (65), eastward past Great Marlow (57) to Bourne End (54), and southward to Taplow and Maidenhead (4934), receiving the Loddon on the right near Shiplake above Henley. Winding in a south-easterly direction, it passes Eton and Windsor (4314), Datchet (4112), Staines (36), Chertsey (32), Shepperton (30) and Sunbury (2612), receiving the Coln from the left at Staines, and the Wey from the right near Shepperton. Flowing past Hampton Court, opposite to which it receives the Mole on the right, and past Kingston (2012), it reaches Teddington (1834). Passing Richmond (16) and Kew the river flows through London and its suburbs for a distance of about 25 m., till it has passed Woolwich. Gravesend, the principal town below Woolwich, is 2612 m. from London Bridge. The estuary may be taken to extend to the North Foreland of Kent. In the tideway the principal affluents of the Thames are the Brent at Brentford, the Wandle at Wandsworth, the Ravensbourne at Deptford, the Lea at Blackwall, the Darent just below Erith, and the Ingrebourne at Rainham, besides the Medway.
The basin of the Thames is of curiously composite character. Thus, the upper portion of the system, above the gap at Goring, is a basin in itself, defined on the west and south by the Cotteswold and White Horse Hills and on the east and north by the Chilterns and the uplands of Northamptonshire. But there are several points at which its division from other river basins is only marked by a very low parting. Thus a well-marked depression in the Cotteswolds brings the head of the (Gloucestershire) Coln, one of the head-streams of the Thames, very close to that of the Isborne, a tributary of the upper Avon; the parting between the head-streams of the Thames and the Bristol Avon sinks at one point, near Malmesbury, below 300 ft.; and head-streams of the Great Ouse rise little more than two miles from, and only some 300 ft. above, the middle valley of the Cherwell. The White Horse Hills and the Chilterns strike right across the Thames basin, but almost their entire drainage from either flank lies within it, and similarly a great part of the low-lying Weald, though marked off from the rest of the basin by the North Downs, drains into it through these hills. It may be noted further that the Kennet continues upward the line of the main valley below the Goring gap, and the Cherwell that of the main valley above it. The basin thus presents interesting problems. The existence of wide valleys where the small upper waters of the Cherwell, Evenlode and Coln now flow, the occurrence of waterborne deposits in their beds from the north-west of England and from Wales, and the fact that the Thames, like its lower southern tributaries which pierce the North Downs, has been able to maintain a deep valley through the chalk elevation at Goring, are considered to point to the former existence of a much larger river, in the system of which were included the upper waters of the present Severn, Dee and other rivers of the west. The question, in fact, involves that of the development of a large part of the hydrography of England.
