Page:Experimental researches in chemistry and.djvu/256

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1829.]
On the Manufacture of Optical Glass.
241

be readily formed from dry materials, and that silica might be added with great advantage to the resulting glass; a range of proportions between the three ingredients being permissible, which gave much command over the properties of hardness, colour, weight, refractive and dispersive power, &c., and yet remained within the required range of fusibility. Platinum also was ultimately found to answer perfectly the purpose of retaining the glass; for though at first it was continually liable to failure, yet it was ultimately ascertained that neither the glass nor any of the substances entering into its composition, separate or mixed, had the slightest action upon it. Finally, it was found that several kinds of glass formed of these materials, were in their physical properties fitted to replace flint glass in the construction of telescopes, in some cases apparently even with advantage; since which time the experiments have been unremittingly pursued.

12. The great proportion of oxide of lead in these glasses rendered attention to very minute points essential; for otherwise striæ were inevitably formed, and even the destruction of the apparatus involved. For this reason, after a certain number of trials upon composition had been made, one unvarying set of proportions were adopted, and the attention given altogether to the discovery and establishment of a process which should yield constantly good results. This, as far as it has been carried into effect and proved, it is now my object to describe.

13. The glass with which I have principally worked is a silicated borate of lead, consisting of single proportionals of silica, boracic acid, and oxide of lead. The materials are first purified, then mixed, fused, and made into a rough glass, which is afterwards finished and annealed in a platina tray.

14. Purification of Materials. Oxide of Lead.—The oxide of lead at first used was litharge; but this source occasioned frequent destruction of the platinum trays, in consequence of the existence of particles of metallic lead, which alloying with the platina, rendered it fusible. When red lead was substituted for litharge, the same effect took place, due to the presence of particles of carbonaceous and reducing matter. Both these substances also contained so much iron and other impurities, as to give a deep colour to the glass, far beyond what was expected