Page:Experimental researches in chemistry and.djvu/430

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1857.]
of Gold (and other Metals) to Light.
415

bright sunlight it will appear light brown and almost opake. From behind, the same fluid may appear of a pure blue in both lights, whilst from the side it may appear amethystine or ruby. These differences result from the mixture of reflected and transmitted lights, both derived from the particles, the former appearing in greatest abundance from the front or side, and the latter from behind. The former is seen by common observation in a purer state if a black background be placed behind the fluid; when a white background is there, much of the transmitted light from that source comes to the eye, and the appearance is greatly altered. A mode of observing the former by a strong ray of light and a lens has been already described; but even in that case some effects of transmitted light are observed if the focus is thrown deep into the fluid; and it is only the particles near the surface, whether illuminated by the base or the apex of the cone, which give the nearly pure effect of reflexion. In order to observe the transmitted ray in an unmingled state, a glass tube closed at one end was surrounded with a tube of black paper longer than itself; and with the black surface inwards. When a fluid (or the particles in it) was to be examined, it was put into this tube, and a surface of white paper illuminated by daylight or the sun, regarded through it, other light being excluded from the eye; or the tube was sometimes interposed between the eye and the sky, and sometimes the rays of the sun itself were reflected up to the eye through it. In speaking hereafter of the tints of the light transmitted by the particles (which will of course vary with the proportion of different rays in the original beam of light), a pure white original light is to be understood, but occasionally differently-tinted papers were employed with this tube as sources of different coloured lights. The very oblique angle at which redected light comes to the eye from the diffused particles, is well seen when the lens cone, or a direct ray of the sun, is passed into the fluid and observed from different positions; it is only when the eye is behind and nearly in the line of the ray, that the unmixed transmitted ray is observed. In the dark tube I think that no reflected light arrives at the eye: for if half an inch in depth of water be introduced, white light passes; if a drop of the washed deposit, to be hereafter described, be introduced, the