- pansion of gases, and to this subject the superb experimenter,
its author, has devoted his whole subsequent life. Especially interesting are his observations of the volumes of ethylene and of carbonic acid at temperatures from 20° to 100° and at pressures ranging from an ounce to 5000 pounds to the square inch. As soon as Amagat had obtained these results, he remarked that the "coefficient of expansion at constant volume," as it is absurdly called, that is, the rate of variation of the pressure with the temperature, was very nearly constant for each volume. This accords with the equation of the virial, which gives
dp/dθ = a/([=V]) - d[sum](R̄r̄)/dθ.
Now, the virial must be nearly independent of the temperature, and, therefore, the last term almost disappears. The virial would not be quite independent of the temperature, because if the temperature (i.e., the square of the velocity of the molecules) is lowered, and the pressure correspondingly lowered, so as to make the volume the same, the attractions of the molecules will have more time to produce their effects, and consequently, the pairs of molecules the closest together will be held together longer and closer; so that the virial will generally be increased by a decrease of temperature. Now, Amagat's experiments do show an excessively minute effect of this sort, at least, when the volumes are not too small. However, the observations are well enough satisfied by assuming the "coefficient of expansion at constant volume" to consist wholly of the first term, a/([=V]). Thus, Amagat's experiments enable us to de-
