conductivity of an electrolyte is proportional to the dissociation of ions. Now the molecular conductivity of a fused electrolyte is usually superior to that of a solution. Here is a case, then, in which diminution of volume is accompanied by increased dissociation.
The truth is that several different kinds of dissociation have to be distinguished. In the first place, there is the dissociation of a chemical molecule to form chemical molecules under the regular action of chemical laws. This may be a double decomposition, as when iodhydric acid is dissociated, according to the formula
HI + HI = HH + II;
or, it may be a simple decomposition, as when pentachloride of phosphorus is dissociated according to the formula
PCl_{5} = PCl_{3} + ClCl.
All these dissociations require, according to the laws of thermo-chemistry, an elevated temperature. In the second place, there is the dissociation of a physically polymerous molecule, that is, of several chemical molecules joined by physical attractions. This I am inclined to suppose is a common concomitant of the heating of solids and liquids; for in these bodies there is no increase of compressibility with the temperature at all comparable with the increase of the expansibility. But, in the third place, there is the dissociation with which we are now concerned, which must be supposed to be a throwing off of unsaturated sub-molecules or atoms from the molecule. The molecule may, as I have said, be roughly likened to a solar system. As such,
