- Life.—The part taken by plants and animals in preserving, destroying or reproducing geological formations.
The words destructive, reproductive and conservative, employed in describing the operations of the epigene agents, do not necessarily imply that anything useful to man is destroyed, reproduced or preserved. On the contrary, the destructive action of the atmosphere may turn barren rock into rich soil, while its reproductive effects sometimes turn rich land into barren desert. Again, the conservative influence of vegetation has sometimes for centuries retained as barren morass what might otherwise have become rich meadow or luxuriant woodland. The terms, therefore, are used in a strictly geological sense, to denote the removal and re-deposition of material, and its agency in preserving what lies beneath it.
(A) The Air.
As a geological agent, the air brings about changes partly by its component gases and partly by its movements. Its destructive action is both chemical and mechanical. The chemical changes are probably mainly, if not entirely, due to the moisture of the air, and particularly to the gases, vapours and organic matter which the moisture contains. Dry air seems to have little or no appreciable influence in promoting these reactions. As the changes in question are similar to those much more abundantly brought about by rain they are described in the following section under the division on rain.
Among the more recognizable mechanical changes effected in the atmosphere, one of considerable importance is to be seen in the result of great and rapid changes of temperature. Heat expands rocks, while cold contracts them. In countries with a great annual range of temperature, considerable difficulty is sometimes experienced in selecting building materials liable to be little affected by the alternate expansion and contraction, which prevents the joints of masonry from remaining close and tight. In dry tropical climates, where the days are intensely hot and the nights extremely cold, the rapid nocturnal contraction produces a strain so great as to rival frost in its influence upon the surface of exposed rocks, disintegrating them into sand, or causing them to crack or peel off in skins or irregular pieces. Dr Livingstone found in Africa (12° S. lat., 34° E. long.) that surfaces of rock which during the day were heated up to 137° Fahr., cooled so rapidly by radiation at night that, unable to sustain the strain of contraction, they split and threw off sharp angular fragments from a few ounces to 100 or 200 ℔ in weight. In temperate regions this action, though much less pronounced, still makes itself felt. In these climates, however, and still more in high latitudes, somewhat similar results are brought about by frost.
By its motion in wind the air drives loose sand over rocks, and in course of time abrades and smoothes them. “Desert polish” is the name given to the characteristic lustrous surface thus imparted. Holes are said to be drilled in window glass at Cape Cod by the same agency. Cavities are now and then hollowed out of rocks by the gyration in them of little fragments of stone or grains of sand kept in motion by the wind. Hurricanes form important geological agents upon land in uprooting trees, and thus sometimes impeding the drainage of a country and giving rise to the formation of peat mosses.
The reproductive action of the air arises partly from the effect of the chemical and mechanical disintegration involved in the process of “weathering,” and partly from the transporting power of wind and of aerial currents. The layer of soil, which covers so much of the surface of the land, is the result of the decay of the underlying rocks, mingled with mineral matter blown over the ground by wind, or washed thither by rain, and with the mouldering remains of plants and animals. The extent to which fine dust may be transported over the surface of the land can hardly be realized in countries clothed with a covering of vegetation, though even there, in dry weather during spring, clouds of dust may often be seen blown away by wind from bare ploughed fields. Intercepted by the leaves of plants and washed down to their roots by rain, this dust goes to increase the soil below. In arid climates, where dust clouds are dense and frequent, enormous quantities of fine mineral particles are thus borne along and accumulated. The remarkable deposit of “Loess,” which is sometimes more than 1500 ft. thick and covers extensive areas in China and other countries, is regarded as due to the drifting of dust by wind. Again the dunes of sand so abundant along the inner side of sandy sea-beaches in many different parts of the world are attributable to the same action.
(B) Water.
In treating of the epigene action of water in geological processes it will be convenient to deal first with its operations in traversing the land, and then with those which it performs in the sea. The circulation of water from land to sea and again from sea to land constitutes the fundamental cause of most of the daily changes by which the surface of the land is affected.
1. Rain.—Rain effects two kinds of changes upon the surface of the land. It acts chemically upon soils and stones, and sinking under ground continues a great series of similar reactions there. It acts mechanically, by washing away loose materials, and thus powerfully affecting the contours of the land. Its chemical action depends mainly upon the nature and proportion of the substances which, in descending to the earth, it abstracts from the atmosphere. Rain always absorbs a little air, which, in addition to its nitrogen and oxygen, contains carbonic acid, and in minute proportions, sodium chloride, sulphuric acid and other ingredients, especially inorganic dust, organic particles and living germs. Probably the most generally efficient of these constituents are oxygen, carbonic acid and organic matter. Armed with these reagents, rain effects a chemical decomposition of the rocks on which it falls, and through which it sinks underground. The principal changes thus produced are as follows: (a) Oxidation.—Owing to the prominence of oxygen in rain-water, and its readiness to unite with any substance which can contain more of it, a thin oxidized pellicle is formed on the surface of many rocks on which rain falls, and this oxidized layer if not at once washed off, sinks deeper until a crust is formed over the stone. A familiar illustration of this action is afforded by the rust, or oxide, which forms on iron when exposed to moisture, though this iron may be kept long bright if allowed to remain screened from moist air and rain. (b) Deoxidation.—Organic matter having an affinity for more oxygen decomposes peroxides by depriving them of some part of their share of that element and reducing them to protoxides. These changes are especially noticeable among the iron oxides so abundantly diffused among rocks. Hence rain-water, in sinking through soil and obtaining such organic matter, becomes thereby a reducing agent. (c) Solution.—This may take place either by the simple action of the water, as in the solution of rock-salt, or by the influence of the carbonic acid present in the rain. (d) Formation of Carbonates.—A familiar example of the action of carbonic acid in rain is to be seen in the corrosion of exposed marble slabs. The carbonic acid dissolves some of the lime, which, as a bicarbonate, is held in solution in the carbonated water, but is deposited again when the water loses its carbonic acid or evaporates. It is not merely carbonates, however, which are liable to this kind of destruction. Even silicates of lime, potash and soda, combinations existing abundantly as constituents of rocks, are attacked; their silica is liberated, and their alkalis or alkaline earths, becoming carbonates, are removed in solution. (e) Hydration.—Some minerals, containing little or no water, and therefore called anhydrous, when exposed to the action of the atmosphere, absorb water, or become hydrous, and are then usually more prone to further change. Hence the rocks of which they form part become disintegrated.
Besides the reactions here enumerated, a considerable amount of decay may be observed as the result of the presence of sulphuric and nitric acid in the air, especially in that of large towns and manufacturing districts, where much coal is consumed. Metallic surfaces, as well as various kinds of stone, are there corroded, while the mortar of walls may often be observed to be slowly swelling out and dropping off, owing to the conversion of the lime into sulphate. Great injury is likewise done from a similar cause to marble monuments in exposed graveyards.
The general result of the disintegrating action of the air and of rain, including also that of plants and animals, to be noticed in the sequel, is denoted by the term “weathering.” The amount of decay depends partly on conditions of climate, especially the range of temperature, the abundance of moisture, height above the sea and exposure to prevalent winds. Many rocks liable to be saturated with rain and rapidly dried under a warm sun are apt to disintegrate at the surface with comparative rapidity. The nature and progress of the weathering are mainly governed by the composition and texture of the rocks exposed to it. Rocks composed of particles liable to little chemical change from the influence of moisture are best fitted to resist weathering, provided they possess sufficient cohesion to withstand the mechanical processes of disintegration. Siliceous sandstones are excellent examples of this permanence. Consisting wholly or mainly of the durable mineral quartz, they are sometimes able so to withstand decay that buildings made of them still retain, after the lapse of centuries, the chisel-marks of the builders. Some rocks, which yield with comparative rapidity to the chemical attacks of moisture, may show little or no mark of disintegration on their surface. This is particularly the case with certain calcareous rocks. Limestone when pure is wholly soluble in acidulated water. Rain falling on such a rock removes some of it in solution, and will continue to do so until the whole is dissolved away. But where a limestone is full of impurities, a weathered crust of more or less insoluble particles remains after the solution of the calcareous part of the stone. Hence the relative purity of limestones may be roughly determined by examining their weathered surfaces, where, if they contain much sand, the grains will be seen projecting from the calcareous matrix, and where, should the rock be very ferruginous, the yellow hydrous peroxide, or ochre, will be found as a powdery crust. In limestones containing abundant encrinites, shells, or other organic remains, the weathered surface commonly presents the fossils standing out in relief. The crystalline arrangement of the lime in the organic structures enables them to resist disintegration better than the general mechanically aggregated matrix of the rock. An experienced fossil collector will always search well such weathered surfaces, for he often finds there, delicately
