The composition of this salt seems to have been first discovered by Tournefort in 1700. The experiments of the younger Geoffroy in 1716 and 1723 were still more decisive, and those of Duhamel, in 1735, left no doubt upon the subject. Dr Thomson first pointed out a process by synthesis, which has the advantage of being very simple, and at the same time rigidly accurate, resulting from his observation that when muriatic gas and ammoniacal gas, both as dry as possible, are brought in contact with each other, they always combine in equal volumes.
The first attempt to manufacture sal-ammoniac in Europe was made, about the beginning of the 18th cen tury, by Mr Goodwin, a chemist of London, who appears to have used the mother ley of common salt and putrid urine as ingredients. The first successful manufacture of sal- ammoniac in this country was established in Edinburgh by Dr Hutton and Mr Davy, about the year 1760. It was first manufactured in France about the same time by Baume . Manufactories of it were afterwards established in Germany, Holland, and Flanders.
Chloride of ammonia is now manufactured in large quan tity from the crude carbonate of ammonia obtained in gas works, or from the destructive distillation of animal matter. This salt is changed into chloride by the addition of hydrochloric acid or the mother liquor of salt-works, called bittern, containing the chlorides of calcium and magnesium. When hydrochloric acid is not easily got for neutralisation, the crude gas liquor is transformed into sulphate, and this is mixed with an equivalent quantity of common salt. During the subsequent evaporation the sulphate of soda separates in hard granular crystals, which are apt to adhere to the sides of the boiler. The liquor is agitated to prevent this adhesion taking place, and assist in the separation of the sulphate of soda. The sulphate of soda is removed by drainers as it is formed, and the mother liquor boiled up to the crystallising point, and run off into coolers. The crystals of impure muriate of am monia are dried carefully and subsequently sublimed.
Sal-ammoniac occurs usually in the form of a hard, white cake, opaque, or only slightly translucent. Its taste is cooling, saline, and rather disagreeable. It dissolves in 272 parts of water at 18 7 C. with great reduction of tem perature, and in about an equal weight of water at the boiling-point. The feathery crystals it forms are found on microscopic examination -to be masses of cubes or octahedrons; their specific gravity is about 1 5. When exposed to a moist atmosphere, the salt gradually absorbs water, and deliquesces, though very slowly, becoming slightly acid. When heated, it sublimes unaltered in a white smoke, having a peculiar smell, very characteristic of sal-ammoniac. If a cold body be presented to this smoke, the sal-ammoniac condenses on it, and forms a white crust. When thus sublimed, it has the property of carrying along with it various bodies, which, when heated by themselves, are perfectly fixed.
For the other ammoniacal salts see Chemistry.
AMMONIACUM, or Ammoniac, a gum-resinous exuda tion from the stem of a perennial herb (Dorema ammonia- cum) belonging to the natural order Umbelliferse. The- plant grows to the height of 8 or 9 feet, and its whole stem is pervaded with a milky juice, which oozes out on an incision being made at any part. This juice quickly hardens into round tears, forming the "tear ammonia- cum " of commerce. Lump ammoniacum, the other form in which the substance is imported, consists of aggrega tions of tears, frequently incorporating large quantities of the fruits of the plant itself, as well as other foreign bodies. In order to free lump ammoniacum from these impurities, it has to be melted and strained, operations which depre ciate its therapeutical value. Ammoniacum has a faintly foetid unpleasant odour, which becomes more distinct on heating ; externally it possesses a reddish yellow appear ance, and when the tears or lumps are freshly fractured they exhibit an opalescent lustre. It is chiefly collected in the province of Irak in Persia ; but some quantity is also produced in the Punjab, and comes to the European market by way of Bombay. Its composition, according to Hagen, is resin, 68 6; gum, 19 3; gluten, 5 4; volatile* oil and water, 2 8; extractive, &c., 3 9. Ammoniacum is closely related to assafoetida, not only in the plant yielding it, but also in its therapeutical effects. It may be used aa a substitute for assafoetida, although, containing a much smaller proportion of volatile oil, its effect is less powerful. Internally it is used in conjunction with squills in bronchial affections ; and in asthma and chronic colds it is found useful. It is, however, more used externally in the form of plasters, as a discutient or resolvent application in indo lent tumours, affections of the joints, &c.
African ammoniacum is a totally different substance, though often confounded with the real gum-resin, which is produced only in the East. It is the product of an un known plant growing in North Africa, and occasionally shipped to our markets from Marocco. It is a dark- coloured gum-resin, possessed of a very weak odour and a persistent acrid taste. A considerable commerce in it is carried on between Mogador and Alexandria, where it is in demand for purposes of fumigation.