Page:Encyclopædia Britannica, Ninth Edition, v. 20.djvu/147

PYROTECHNY 135 mental fact of pyrotechny, that, with proper attention to the chemical nature of the substances employed, solid mixtures (compositions or fuses} may be prepared which contain within themselves all that is essential for the pro- duction of fire. If nitre and chlorate of potash, with other salts of nitric and chloric acids and a few similar compounds, be grouped together as oxidizing agents, most of the other materials used in making firework compositions may be classed as oxidizable substances. Every composition must contain at least one sample of each class : usually there are present more than one oxidizable substance, and very often more than one oxidizing agent. In all cases the proportions by weight which the ingredients of a mixture bear to one another is a matter of much importance, for it greatly affects the manner and rate of combustion. The most important oxidizable substances employed are charcoal and sulphur. These two, it is well known, when properly mixed in certain proportions with the oxidizing agent nitre, constitute gunpowder ; and gunpowder plays an important part in the construction of most fireworks. It is sometimes employed alone, when a strong explosion is required ; but more commonly it is mixed with one or more of its own ingredients and with other matters. In addition to charcoal and sulphur, the following oxidizable substances are more or less employed : many compounds of carbon, such as sugar, starch, resins, &c. ; certain metallic compounds of sulphur, such as the sulphides of arsenic and antimony ; a few of the metals themselves, such as iron, zinc, magnesium, antimony, copper. Of these metals iron (cast-iron and steel) is more used than any of the others. They are all employed in the form of powder or small filings. They do not contribute much to the burning power of the composition; but when it is ignited they become intensely heated and are discharged into the air, where they oxidize more or less completely and cause brilliant sparks and scintillations. Sand, sulphate of potash, calomel, and some other sub- stances, which neither combine with oxygen nor supply it, are sometimes employed as ingredients of the compositions in order to influence the character of the fire. This may be modified in many ways. Thus the rate of combustion may be altered so as to give anything from an instantane- ous explosion to a slow fire lasting many minutes. The flame may be clear, smoky, or charged with glowing sparks. But the most important characteristic of a fire one to which great attention is paid by pyrotechnists is its colour, which may be varied through the different shades and combinations of yellow, red, green, and blue. These colours are imparted to the flame by the presence in it of the heated vapours of certain metals, of which the following are the most important: sodium, which gives a yellow colour ; calcium, red ; strontium, crimson ; barium, green; copper, green or blue, according to cir- cumstances. Suitable salts of these metals are much used as ingredients of fire mixtures ; and they are decom- posed and volatilized during the process of combustion. Very often the chlorates and nitrates are employed, as they serve the double purpose of supplying oxygen and of imparting colour to the flame. The number of fire mixtures actually employed is very great ; for the requirements of each variety of firework, and of almost each size of each variety, are different. Moreover, every pyrotechnist has his own taste in the matter of compositions. They are capable, however, of being classified according to the nature of the work to which they are suited. Thus there are rocket-fuses, gerbe- fuses, squib-fuses, star-compositions, &c. ; and, in addition, there are a few which are essential in the construction of most fireworks, whatever the main composition may be. Such are the starting-powder, which first catches the fire, the bursting-powder, which causes the final explosion, and the quick-match (cotton-wick, dried after being saturated with a paste of gunpowder and starch), employed for con- necting parts of the more complicated works and carrying the fire from one to another. Of the general nature of fuses an idea may be had from the following two examples, which are selected at hazard from among the numerous recipes for making, respectively, tourbillion fire and green stars : Tourbillion. Meal gunpowder ...... 24 parts. Nitre 10 Sulphur 7 Charcoal 4 Steel filings 8 Green Stars. Chlorate of potash ...16 parts. Nitrate of baryta ... 48 Sulphur ............... 12 Charcoal ............... 1 Shellac .................. 5 Calomel ............... 8 Sulphide of copper... 2 Although the making of compositions is of the first importance, it is not the only operation with which the pyrotechnist has to do ; for the construction of the cases in which they are to be packed, and the actual processes of packing and finishing, require much care and dexterity. These cases are made of paper or pasteboard, and are generally of a cylindrical shape. In size they vary greatly, according to the effect which it is desired to produce. The relations of length to thickness, of internal to external diameter, and of these to the size of the openings for discharge, are matters of extreme importance, and must always be attended to with almost mathematical exactness and considered in connexion with the nature of the com- position which is to be used. There is one very important property of fireworks that is due more to the mechanical structure of the cases and the manner in which they are filled than to the precise chemical character of the composition, i.e., their power of motion. Some are so constructed that the piece is kept at rest and the only motion possible is that of the flame and sparks which escape during combustion from the mouth of the case. Others, also fixed, contain, alternately with layers of some more ordinary composition, balls or blocks of a special mixture cemented by some kind of varnish ; and these stars, as they are called, shot into the air, one by one, like bullets from a gun, blaze and burst there with striking effect. But in many instances motion is imparted to the firework as a whole, to the case as well as to its contents. This motion, various as it is in detail, is almost entirely one of two kinds, rotatory motion round a fixed point, which may be the centre of gravity of a single piece or that of a whole system of pieces, and free ascending motion through the air. In all cases the cause of motion is the same, viz., that large quantities of gaseous matter are formed by the combus- tion, that these can escape only at certain apertures, and that a backward pressure is necessarily exerted at the point opposite to them. When a large gun is discharged, it recoils a few feet. Movable fireworks may be regarded as very light guns loaded with heavy charges; and in them the recoil is therefore so much greater as to be the most noticeable feature of the discharge; and it only requires proper contrivances to make the piece fly through the air like a sky-rocket or revolve round a central axis like a Catherine wheel. Beauty of motion is hardly less important in pyrotechny than brilliancy of fire and variety of colour. The following is a brief description of some of the forms of fire- work most employed : Fixed Fires. Theatre fires consist of a slow composition which may be heaped in a conical pile on a tile or a flagstone and lit at the apex. They require no cases. Usually the fire is coloured, green, red, or blue ; and beautiful effects are obtained by illumin- ating buildings with it. It is also used on the stage ; but, in that