Page:Experimental researches in chemistry and.djvu/295

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On the Manufacture of Optical Glass.
[1829.

more of that (oxide of lead) which is considered as the vulnerable part, than does either of the former kinds.

105. The superficial changes of glass which interfere with its optical uses are of two kinds. The one is shown by a tarnish upon the surface, which when strong is iridescent. It is quickly produced by the intentional presence of sulphuretted hydrogen, which acting upon the oxide of lead present, reduces it, and forms a sulphuret of lead. It takes place only with flint glass, and is in every case produced either by sulphuretted hydrogen or other sulphuretted vapours. In plate glass the change is of another kind, and is shown by the appearance of minute vegetation's or crystallizations, which spread, obstructing the light wherever they occur. Mr. Dollond, who has shown me cases of both kinds of injury in flint and plate glass, is inclined to believe that the latter has, during his long experience, proved most injurious.

106. From the commencement of the experiments it was expected that these heavy optical glasses would tarnish more than flint glass; but as specimens of borate of lead and other dense compounds of that metal had been retained in an ordinary atmosphere, without any particular precautions, for long periods of time, yet without tarnishing, there was encouragement to continue the investigations; and though when specimens were put into atmospheres purposely contaminated with sulphuretted hydrogen, they tarnished quickly, and much more than any flint glass, yet it did not follow that they would of necessity tarnish in the telescope; especially as, being (from the construction of the achromatic object-glass) enclosed by the tube and the crown or plate glass lens, they would he considerably protected, and at the same time would admit of the intentional application of extraneous chemical protectors.

107. The kind of protection which occurs to the mind is the application of such substances to the interior of the tube as, having a strong attraction for sulphuretted vapours, should continually retain the atmosphere within free from their presence. Carbonate of lead, precipitated borate of lead or finely ground litharge, mixed with the pigment which is usually applied to blacken the inside of the telescope that all extraneous light may be absorbed, will probably effect this purpose completely.

108. A very curious and important influence of alkali in facil-