Page:Experimental researches in chemistry and.djvu/444

This page has been proofread, but needs to be validated.
1857.]
of Gold (and other Metals) to Light.
429

substance on which they are deposited. They have all the chemical reactions of gold, being, though so finely divided, insoluble in the fluids that refuse to act on the massive metal, and soluble in those that dissolve it, producing the same result. Heat makes these divided particles assume a ruby tint, yet such heat is not likely to take away their metallic character, and when heated they still act with chemical agents as gold. Pressure then confers the green colour, which heat takes away, and pressure re confers. All these changes occur with particles attached to the substances which support them by the slightest possible mechanical force, just enough indeed to prevent their coalescence and to keep them apart and in place, and yet offering no resistance to any chemical action of test agents, as the acids, &c., not allowing any supposition of chemical action between them and the body supporting them. Still this gold, unexceptionable as to metallic state, presents different colours when viewed by transmitted light. Ruby, green, violet, blue, &c. occur, and the mere degree of division appears to be the determining cause of many of these colours. The deflagrations by the voltaic battery lead to the same conclusion.

The gold films produced by phosphorus have every character belonging to the metallic state. When thick, they are in colour, lustre, weight, &c. equal to gold-leaf; but in the unpressed state, their transmitted colour is generally grey, or violet-grey. The progression of their lustre and colour is gradual from the thickest to the thinnest, and the same is generally true, if thick films are gradually thinned and dissolved whilst Boating on solvents; the thick and the thin films must both be accepted as having the same amount of evidence for their metallic nature. When subjected to chemical agents, both the thick and the thin films have the same relations as pure metallic gold. These relations are not changed by the action of heat, yet heat shows the same peculiar effect that it had with preparations of gold obtained by beating, or by electric deflagrations. The remarkable and characteristic effect of pressure is here reproduced, and sometimes with extraordinary results; since from the favourable manner in which the particles are occasionally divided and then held in place on the glass, the mere touch of a finger or card is enough to produce