HYD RO CAR BO NS, H ALO GE NAT ED: M ETH OD 1003, Issue 3, dated 1 5 Ma rch 2003 Page 4 o f 7
Compound
Range mg/m3
Sample Size
Bias %
Precision Overall Measurement
Benzyl chloride Bromoform Carbon tetrachloride Chlorobenzene Chlorobromomethane Chloroform o-Dichlorobenzene p-Dichlorobenzene 1,1-Dichloroethane 1,2-Dichloroethylene* Ethylene dichloride Hexachloroethane 1,1,1-Trichloroethane Tetrachloroethylene 1,1,2-Trichloroethane 1,2,3-Trichloropropane
2-8 3-10 65-299 183-736 640-2655 100-416 150-629 183-777 212-838 475-1915 195-819 5-25 904-3790 655-2749 26-111 163-629
10 L 10 L 15 L 10 L 5L 15 L 3L 3L 10 L 3L 3L 10 L 3L 3L 10 L 10 L
! 8.4 ! 1.3 ! 1.6
0.096 0.071 0.092 0.056 0.061 0.057 0.068 0.052 0.057 0.052 0.079 0.121 0.054 0.052 0.057 0.068
0.3 3.4 1.3 ! 1.9 ! 4.3 2.6 ! 2.9 ! 2.0 ! 6.6 ! 0.6 ! 7.2 ! 9.0 2.1
Accuracy ±%
Desorption Efficiency
25.6 14.0 18.0 11.0 14.0 11.6 13.7 12.5 12.4 11.3 15.7 25.4 10.6 15.1 17.5 14.2
94% @ 96-303 µg 94% @ 35-111 µg 93% @ 32-4800 µg 92% @ 111-7100µg 98% @39-13,000µg 97% @ 24-7400 µg 94% @ 19-1900 µg 98% @ 25-2700 µg 101% @20-8000 µg 101% @19-9500 µg 94% @ 2.5-2500 µg 98% @ 34-756.8 µg 100%@23-11000µg 95% @ 8-8000 µg 100% @18-1200 µg 99% @ 21-6000 µg
0.031 0.043 0.037 0.025 0.051 0.047 0.013 0.022 0.011 0.017 0.012 0.014 0.018 0.013 0.010 0.027
- mixed isomers used (i.e., cis- and trans-).
REFERENCES: [1] NIOSH [1977]. Docum entation of the NIOSH Validation Tests, S101, S110, S113, S114, S115, S122, S123, S126, S133, S134, S135, S281, S314, S328, S335, S351, U.S. Department of Health, Education, and W elfare, Publ. (NIOSH) 77-185, available as Stock No. PB 274-248 from NT IS, Springfield, VA 22161. [2] NIOSH [1994]. Hydrocarbons, Halogenated: Method 1003. In: Eller PM, Cassinelli ME, eds. NIOSH m anu al of analytical m etho ds. 4 th ed. Cincinnati, OH: U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, DHHS (NIOSH) Publication No. 94-113. [3] NIOSH [1994]. Trichloroethylene: Method 1022. In: Eller, PM, Cassinelli, ME, eds. NIOSH m anual of ana lytical metho ds. 4 th rev. ed. Cincinnati, OH: U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, DHHS (NIOSH) Publication No. 94-113. [4] Pende rgrass S M [1 998 ]. Bac kup Data R epo rt for N MA M 1003 , Issue 3 M etho d Developm ent. Cincinnati, OH: National Institute for Oc cupational Safety and Hea lth, (unpublished, Dec em ber). [5] NIO SH [1977]. Ca rbon tetrac hloride : Me thod S31 4, NIOS H m anu al of analytical m etho ds, 2 nd ed., Vol. 1, Cincinnati, OH: U.S. Department of Health, Education, and W elfare, (NIOSH) Publication 77157-A. [6] Ibid., S133. [7] Ibid., S113. [8] Ibid., Vol 3., S351, (NIOSH) Publication 77-157-C. [9] Ibid., S135. [10] Ibid., S281. [11] Ibid., Vol. 2, S123, (NIOSH) Publication 77-157-A. [12] Ibid., S110. [13] Ibid., S122. [14] Ibid., Vol 3, S328, (NIOSH) Publication 77-157-C. [15] Ibid., S335. [16] Ibid., Vol. 2, S134, (NIOSH) Publication 77-157-A. [17] Ibid., S126.
METHOD REVISED BY: Stephanie M. Pendergrass, NIOSH/ DART.
NIOSH Manual of Analytical Methods (NMAM), Fourth Edition
Ref. 4 4 4,5 4,6 4,7 4,8 4,9 4,10 4,11 4,12 4,13 4 4,14 4,15 4,16 4,17
