TRIPHENYL TIN CHLORIDE (as Sn) 5527 C18H15ClSnMW: 385.46CAS: 639-58-7RTECS: WH6860000 |
| METHOD: 5527, Issue 1 |
EVALUATION: PARTIAL |
Issue 1: 15 March 2003 |
| OSHA: 0.1 mg / m3 as Sn | PROPERTIES:solid; MP 108 °C; BP 240°°C |
| NIOSH: 0.1 mg / m3 as Sn (skin) | |
| ACGIH: 0.1 mg / m3 as Sn |
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| SYNONYMS: Chlorotriphenylstannane, Chlorotriphenyltin, Fentin Chloride, Triphenylchlorostannane, Triphenylchlorotin |
| SAMPLING | MEASUREMENT |
| SAMPLER: FLOW RATE: VOL-MIN: -MAX: SHIPMENT: SAMPLE STABILITY: BLANKS: |
FILTER (37-mm, 5-µm polyvinyl chloride) 1 to 4 L / min 100 L 2000 L Routine Stable at ambient temperature for 28 days 2 to 10 field blanks per set |
TECHNIQUE: ANALYTE: FILTER DESORPTION: SEPARATION: ICP: DETECTOR WAVELENGTH: INJECTION VOLUME: CALIBRATION: RANGE: ESTIMATED LOD: PRECISION (Ŝr): |
HIGH PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC) / INDUCTIVELY COUPLED ARGON PLASMA ATOMIC EMISSION SPECTROSCOPY (ICP-AES) Tin 5 mL tropolone/water/methanol (0.02:22:78) HPLC, reverse phase; C18), 250 x 4.60-mm, 5-μm, Kingsorb 5 or equivalent Operating under conditions for organic compound 189.9 nm 50 μL Standard solutions of triphenyl tin chloride in methanol 10 μg to 225 μg per sample [1] 3 μg per sample (instrumental) [1] 0.034 [1] |
| ACCURACY | |||
| RANGE STUDIED: BIAS: OVERALLPRECISION (ŜrT): ACCURACY: |
Not studied Not determined Not determined Not determined | ||
| APPLICABILITY: The working range of this method is 0.01 to 0.2 mg/m3 as tin in a 1000 L air sample. |
| INTEREFERENCES: Other organotin compounds with the same retention time as triphenyl tin chloride would interfere. |
| OTHER METHODS: There are no other NIOSH methods specifically for triphenyl tin chloride. Other organotin compounds have been determined by NIOSH Method 5504 [2] which uses the analytical technique of HPLC-atomic absorption spectroscopy. |
NIOSH Manual of Analytical Methods (NMAM), Fourth Edition
