mass-flow or a dry-gas meter, may be used. The following instructions are for the soap-bubble meter. If another instrument is used, equivalent procedures should be followed.
(1) Set up the apparatus as shown in Figure 1.
(2) Make certain that the rechargeable batteries will power the pump for the entire sampling interval by one of the following methods: 1) run the pump for that length of time, checking for satisfactory operations; 2) test the battery independently of the pump using a current capacity tester [17]. Fully recharge the batteries.
(3) Turn the pump on and moisten the inner surface of the soap-bubble meter with the soap solution. Draw bubbles upward until they travel the entire length of the buret without breaking.
(4) Adjust the pump to the desired nominal flow rate. Check the water manometer. The pressure drop across the sampler should not exceed 2.5 cm Hg (13 inches) of water.
(5) Start a soap bubble in the buret and measure the time, with a stopwatch, that it takes to traverse two calibration marks. For a 1000-mL buret, a convenient calibration volume is 500 mL. Repeat the determination at least twice more. Average the results and calculate the flow rate by dividing the calibration volume by the average time.
(6) Record the following data:
a. volume measured
b. elapsed time
c. pressure drop
d. air temperature
e. atmospheric pressure
f. serial number of the pump
g. pump model
h. date and name of operator
(7) If the sampling pump used for sample collection uses a variable area flow meter (rotameter) for flow rate indication, the calibrated flow rate must be adjusted for the actual air pressure and temperature during sampling [18]. The expression for this correction is as follows.
NOTE: This correction is not used for non-rotameter sampling pumps.
V (Corrected volume, L) = Q t (PcTs/PsTc)0.5
| where: | Q = indicated flow rate (L/min) |
| t = sampling time (min) | |
| Pc = pressure during calibration of sampling pump |
