DR. A. SCOTT ON THE COMPOSITION OF WATER BY VOLUME.
553
Hydrogen as before—
Volume 45.6 = 3823.5Temperature = 15.4° C.
millims. | millims. | |||
Height of mercury in manometer tube on scale | = | 115.8 | on cathetometer | = 7.1 |
Height of„ mercury in„ volume tube on scale | = | 115.5 | on cathetometer„ | = 6.8 |
Height of mercury in Correction= | + | 0.3 | + 0.3 |
millims. | ||
Barometer 777.6 − 25.7 | = 751.9 | |
Pressure of aqueous vapour | = | 13.0|
Pressure of hydrogen = 751.9 + .3 − 13.0 | = 739.2 |
Residue (of oxygen)—
Volume 8.6 = 56.5Temperature = 15.4° C.
millims. | millims. | |||
Height of mercury in manometer tube on scale | = | 491.9 | on cathetometer = | 10.0 |
Height of„ mercury in„ volume tube on scale | = | 484.7 | on cathetometer„ = | 2.8 |
Height of mercury in Correction | + | 7.2 | + | 7.2 |
millims. | ||
Barometer = 777.7 − 25.4 | = 752.3 | |
Pressure of aqueous vapour | = | 13.0|
Pressure of gas = 752.3 + 7.2 − 13.0 | = 746.5 |
On analysis of residue .6 of unabsorbable gas remained after treatment with potassium hydrate and pyrogallol; no carbon dioxide being detected.
Total oxygen volume reduced to 0° C. and 760 millims. pressure, becomes
millims. | |||
3881.0 × 737.8760.0 × 273.0288.4 | = | 3566.4 | |
Residual volume | |||
746.5760.0 × 273.0288.4 | 56.5 ×= | 52.5 | |
.6 | |||
Hydrogen volumes become Oxygen in residue | = | 51.9 | |
Hydrogen volumes become | |||
3819.6 × 738.6760.0 × 273.0288.35 | = | 3514.4 | |
3823.5 × 739.2760.0 × 273.0288.4 | = | 3520.2 | |
Hydrogen volumes become Total hydrogen volume | = | 7034.6 |