Page:Proceedings of the Royal Society of London Vol 69.djvu/107

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Some Physical Properties of Nitric Acid Solutions.
99


Results at 4'

Contraction

Contraction

Percent-

Contrac- tion

calculated i'rom the


Difference.


calculated from the


Difference.


age.


observed.


4 per cent.



21 per cent.





origin.



origin.



18-44


3702


3738


-36


3758


-56


19-37


3881


3924


-43


3912


-31


20-68


4022


4168


-164


4105


-73


21-43


4181


4346


-165


4222


-41


21-95


4291


4440


-149


4302


-11


Results at 14'2.


19-37


3685


3706


-21


3712


-27


19-72


3722


3767


-43


3750


-34


20-24


3803


3876


-73


3834


-31


20-68


3849


3959


-110


3900


-51


21-38


3952


4096


-14*


4008


-56


21-98


4087


4206


-119


4099


-12


Results at 24-2.


18 -44


3360


3389


-29


3454


-94


19-37


3486


3541


-51


3589


-103


20-24


3688


3717


-29


3715


-27


20-68


3724


3796


-74


3779


-55


21-43


3822


3932


-110


3887


55


21-98


3959 4032


-63


3967


-8


22-37


4016


4103


-89


4024



It will be evident that in all cases the results up to 19'37 lie upon the straight line drawn from the 4 per cent, origin, and on the other hand those 21-98 upwards lie upon the straight line from the 21 per cent, origin, while the intermediate values lie below both lines. As it would appear from a consideration of the examples given above that the observations in the vicinity of critical points may be represented in certain cases as on either, and in others as on neither of the lines meeting at those points, then such points may be regarded as in a certain sense ideal, and the phenomena as continuous. Some such possibility might tend to overcome the mental difficulty experienced by certain writers as regards the manifestation of sudden irregularities, and throughout the whole course of events from commencement to conclusion one is dealing with combined water and free water, with combined acid and free acid, and in the more dilute solutions with integral or undecomposed molecules as also with their respective ions.