Page:Proceedings of the Royal Society of London Vol 69.djvu/122

This page needs to be proofread.
114
Messrs. V. H. Veley and J. J. Manlcy.


Percentage concentration.


Temperature coefficients


I

Percentage Temperature i concentra- coefficient i tion. 10~ 6 .


Percentage concentra- tion.


Tempera- ture coeffi- cients

io- r v


2-19


95


41 -45 293


75-23


447


3-85


94


44 -69 326


78 -07


447


6-76


108


46 -90 340


81-12


484


9-29


122


49-12 352


84-11


441


11-88


128


51 -00 372


85-86


442


16-11


156


54 -63 386


87-26


455


18-27


177 57 -00


388


89-88


441


21-66


190 60-33


40(3


91-24


465


25-07


217 63 -07


420


92-82


488


29 -40


231 66 -GO


419


95-66


483


32 -50


267 67 -92


432


98-67


484


34-26


280 70 -04


418


99-87


490


36-68


279 71 -51


432

39-11


292


74-03


433


It will be observed that these temperature coefficients increase gradually but by no means uniformly with increase of percentage ; in both cases only very small differences are measured, which accounts for the slight irregularities. There is probably some function con- necting these two factors, but from certain trials made it does not appear to be of a simple character.

The value for the 60-33 per cent, acid, namely, 0-000406 is not widely different from that 0-000424 given by van der Willigen for his sample of 58*89 per cent, concentration.

mil. Results.

The results for /X D reduced to a uniform temperature are set forth in the following table :

II


1


Percentage


Percentage


Percentage


concen-


14'2

^n


conceit -


jUj, 14 '-. concen-


V 4 ' 2 -


tration.


t ration.


tration.



2-19


1 -336208


41 -45


1 -38S788 75 -23


1 -405599


3-85


338434


44 -69


392305 78 -07


405091


6-76


342298


46-90


394496 81 '12


404504


9-29


345824


49-12


396699 84-11


403427


11-88


349371


51-0


398435 85 '80


402924


16-11


355107


54-63


401017 87 -20


402412


18-27


358541


57-0


402440 89 '88


401419


21-66


363091


60-33


404080 91 -29


401017


25-07


365152


63-07


405157 92 -82


400249


29-40


374225


66-60


4058(30 95 '66


398148


32-60


377798


67-92


405985 98 '67


396980


34-26


380354


70-04


406094 99 -87


397167 (


36-68


383039


71-57


406046



39-11


386262


74-63


405696