Page:Reflections on the Motive Power of Heat.djvu/185

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MOTIVE POWER OF HEAT.
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28. The preceding investigations, being founded on the approximate laws of compressibility and expansion (known as the law of Mariotte and Boyle, and the law of Dalton and Gay-Lussac), would require some slight modifications to adapt them to cases in which the gaseous medium employed is such as to present sensible deviations from those laws. Regnault's very accurate experiments show that the deviations are insensible, or very nearly so, for the ordinary gases at ordinary pressures; although they may be considerable for a medium, such as sulphurous acid, or carbonic acid under high pressure, which approaches the physical condition of a vapor at saturation; and therefore, in general, and especially in practical applications to real air-engines, it will be unnecessary to make any modification in the expressions. In cases where it may be necessary, there is no difficulty in making the modifications, when the requisite data are supplied by experiment.

29.[1] Either the steam-engine or the air-engine, according to the arrangements described above, gives all the mechanical effect that can possibly be obtained from the thermal agency employed. For

  1. This paragraph is the demonstration, referred to above, of the proposition stated in § 13, as it is readily seen that it is applicable to any conceivable kind of thermodynamic engine.