Ostwald defines peptization as the phenomenon opposed to coagulation.
Taylor prefers a new term, "solation," which he applies to all cases of gel→sol transformations, and incidentally he urges the adoption of "gelation" to define all cases of sol→gel transformations instead of coagulation or pectization.
"Pectization," another of Graham's terms, is rapidly dying out. The word "coagulation" covers all cases of pectization and therefore why preserve an unnecessary term? Furthermore, why adopt the new term "gelation" proposed by Taylor. "Coagulation" is adequate. Of course, if it is decided to name jellies (stiffened sols) "gels," then the word "gelation" would be a good one to describe the "setting" of the gel or the stiffening of the sol.
Elimination of some synonymous terms is decidedly necessary from the list of names applied to the two more or less distinct classes or systems of colloid dispersions. For example, these two systems are variously named as follows:
| Authors | |||
| Noyes[1] | Colloidal solutions | Colloidal suspensions | |
| Hardy,[2] Zsigmondy[3] | Reversible colloids | Irreversible colloids | |
| Billitzer[4] | Baser colloids | Typical or genuine colloids | |
| Billitzer„ | Hydrophilous colloids | Anhydrophilous colloids | |
| Henri[5] | Stable colloids | Unstable colloids | |
| Perrin, Freundlich,[6] Neumann[7] | Lyophilic colloids | Lyophobic colloids | |
| Bary[8] | Dissolving colloids | Electrical colloids | |
| Wo. Ostwald[9] | Emulsion colloids | Suspension colloids | |
| von Weimarn[10] | Emulsoids | Suspensoids | |
| Burton[11] | Gelatinizing type | Non-gelatinizing type | |
The terms "emulsoid" and "suspensoid" are very popular. "Lyophilic" and "lyophobic" are very expressive. The "stable-unstable" and the "reversible-irreversible" terms should also be abolished, since they describe the conduct and changes in state of colloids when subjected to external conditions and are not always sharply defined. For example, hydrous ferric oxide sol is fairly stable in the presence of neutral electrolyte (much more so than colloidal gold or platinum), while it is irreversible when evaporated to dryness. Most writers classify it with the suspensoids, although Taylor calls it an emulsoid (since if it be evaporated not quite to dryness it is partially reversible). In reality it belongs to neither of these two generally accepted classes; its properties place it midway between the two, nearer the suspensoid than the emulsoid class. All the hydrous oxides of the basic or acidic elements act similar to hydrous ferric oxide.
On account of this confusion of classification Bancroft[12] has suggested that the distinction between these two groups be done away with. He prefers to classify colloidal systems according as to whether water or the more mobile phase, is the internal or the external phase and states: "While we are reasonably sure that colloidal gold is a solid and that colloidal oil is a liquid, the two behave exactly alike when both are suspended electrically."
This suggestion is along the proper lines, but is too sweeping, since colloidal gold and colloidal oil do not behave alike.
After a consideration of all the terms, it would seem that "lyophilic" and "lyophobic," or more special derivatives, "hydrophobic" are the least objectionable terms, since most colloids answer to one of these designations. When our knowledge of colloids becomes exact enough to sharply differ-
- ↑ J. Am. Chem. Soc., 27, 85 (1905).
- ↑ Proc. Roy. Soc., 66, 95 (1900).
- ↑ "Kolloidchemie."
- ↑ Z. physik. Chem., 45, 307 (1903).
- ↑ Z. physik. Chem., 51, 29 (1905).
- ↑ "Kapillarchemie."
- ↑ Koll. Z., 3, 80 (1908).
- ↑ J. Chim. Phys., 10, 437 (1912).
- ↑ "Handbook of Colloid Chemistry."
- ↑ "Grundzüge der Dispersoidchemie."
- ↑ "Physical Properties of Colloidal Solutions."
- ↑ J. Phys. Chem., 18, 549–558 (1914).
