Page:Scientific Memoirs, Vol. 1 (1837).djvu/362

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350
M. CLAPEYRON ON THE MOTIVE POWER OF HEAT.

will be represented geometrically by the area comprised between the axis of the abscisses, the two coordinates , , and the portion of a hyperbola .

Fig. 1

Supposing, again, that the body is removed and that the dilatation of the gas continues in an inclosure impermeable to heat; then a part of its sensible caloric becoming latent, its temperature will diminish and its pressure will continue to decrease in a more rapid manner and according to an unknown law, which law might be represented geometrically by a curve , the abscissæ of which would be the volumes of the gas, and the ordinates the corresponding pressures: we will suppose that the dilatation of the gas has continued until the successive reductions which its sensible caloric experiences have reduced the temperature of the body to the temperature of the body ; its volume will then be , and the corresponding pressure . It will also be evident from the same reasoning, that the gas during this second part of its dilatation will develop a quantity of mechanical action represented by the area of the mixtilinear trapezium .

Now that the gas is brought to the temperature of the body , let us bring them together: if we compress the gas in an inclosure impermeable to heat, but in contact with the body , the temperature of the gas will tend to rise by the evolution of latent heat rendered sensible by compression, but will be absorbed in proportion by the body , so that the temperature of the gas will remain equal to . The pressure will increase according to the law of Mariotte: it will be represented geometrically by the ordinates of a hyperbola , and the corresponding abscisses will represent the corresponding volumes. Suppose the compression to be increased until the heat disengaged and absorbed by the body is precisely equal to the heat communicated to the gas by the