Of the Action of Solutions of Neutral Salts on Lead.
The property which pure aërated water possesses of corroding lead is variously affected by foreign ingredients which it may hold in solution.
Of these modifying substances none are more remarkable in their action than the neutral salts, which all impair the corrosive power of the water. Important practical consequences flow from that action; for it involves no less than the possibility of employing lead for most of the economical purposes to which the ingenuity of man has applied that useful metal. The first experimentalist who made it an object of attention was Guyton-Morveau; whose experiments are imperfect and in some respects erroneous. Having found that distilled water corrodes lead, he proceeded to inquire why no change of the kind takes place in some natural waters; and being aware that most spring and river waters differ from that which has been distilled, chiefly in containing sulphate of lime and muriate of soda, he tried a solution of each of these salts, and discovered that the addition of a certain quantity of either to distilled water takes away from it the power of attacking lead,—that this preservative power is possessed by so small a proportion as a 500th part of sulphate of lime in the water,—and that the nitrates are also probably endowed with the same singular property.[1] Here his researches terminated.
Extending Guyton-Morveau's inquiries to other proportions of the same salts, and likewise to many other neutral salts, I was led to the conclusion, that all of them without exception possess the power of impairing the action of distilled water on lead. At least I found this power to exist in the case of sulphates, muriates, carbonates, hydriodates, phosphates, nitrates, acetates, tartrates, and arseniates.
The degree of this preservative power differs much in different salts. The acetate of soda is but an imperfect preventive when dissolved in the proportion of a hundredth part of the water: white crystals are formed, and the lead loses about a fourth of what is lost in distilled water in the same time. On the contrary, arseniate of soda is a complete preservative when dissolved in the proportion of a 12,000th; and phosphate of soda and hydriodate of potass are almost effectual preservatives in the proportion of a 30,000th part only of the water.[2] Muriate of soda and sulphate of lime hold a middle place between these extremes, and are both of them much more powerful than Guyton-Morveau imagined: the former preserves in the proportion of a 2000th to the water, the latter in the proportion of nearly a 4000th. Nitrate of potass is little superior to the acetate of soda: in the pro-*
- ↑ Annales de Chimie, lxxi. 197.
- ↑ In distilled water containing a 12,000th of anhydrous arseniate of soda three lead rods weighing 71·235 grains became in thirty-three days 71·240; in a solution of a 15,000th the lead, though slightly whitened, retained its weight exactly, weighing at the end, as at the beginning, of the experiment 62·622 grains. In distilled water containing a 35,000th of anhydrous phosphate of soda, three lead rods, which weighed together 73·949 grains, became in thirty-two days 73·946; and in a comparative experiment with a solution containing a 27,000th they gained 0·015.
