The commoner rock constituents are nearly all oxides; chlorine, sulphur and fluorine are the only important exceptions to this and their total amount in any rock is usually much less than 1%. F. W. Clarke has calculated that a little more than 47% of the earth's crust Chemical Characters.consists of oxygen. It occurs principally in combination as oxides, of which the chief ire silica, alumina, iron oxides, lime, magnesia. potash and soda. The silica functions principally as an acid, forming silicates, and all the commonest minerals of igneous rocks are of this nature. From a computation based on 1672 analyses of all kinds of rocks Clarke arrived at the following as the average percentage composition: SiO2=59.71, Al2O3=15.41, Fe2O3=2.63, FeO=3.52, MgO=4.36, CaO=4.90, Na2O=3.55, K2O=2.80, H2O=1.52, TiO2=0.60, P2O5= 0.22, total 99.22 %. All the other constituents occur only in very small quantities, usually much less than 1 %.
These oxides do not combine in a haphazard way. The potash and soda, for example, with a sufficient amount of alumina and silica, combine to produce felspars. In some cases they may take other forms, such as nepheline, leucite and muscovite, but in the great majority of instances they are found as felspar. The phosphoric acid lime forms apatite. The titanium dioxide with ferrous oxide gives rise to ilmenite. Part of the lime forms lime felspar. Magnesia and iron oxides, with silica crystallize as olivine or enstatite, or with alumina and lime form the complex ferro-magnesian silicates of which the pyroxenes, amphiboles and biotites are the chief. Any excess of silica above what is required to neutralize the bases will separate out as quartz; excess of alumina crystallizes as corundum. These must be regarded only as general tendencies, which are modified by physical conditions in a manner not as yet understood. It is possible by inspection of a rock analysis to say approximately what minerals the rock will contain, but there are numerous exceptions to any rule which can be laid down.
Hence we may say that except in acid or siliceous rocks containing 66% of silica and over, quartz will not be abundant. In basic rocks (containing 60% silica or less) it is rare and accidental. If magnesia and iron be above the average while silica is low olivine Mineral Constitu-tion.may be expected; where silica is present in greater quantity other ferro-magnesian minerals, such as augite, hornblende, enstatite or biotite, occur rather than olivine. Unless potash is high and silica relatively low leucite will not be present, for leucite does not occur with free quartz. Nepheline, likewise, is usually found in rocks with much soda and comparatively little silica. With high alkalis soda-bearing pyroxenes and amphiboles may be present. The lower the percentage of silica and the alkalis the greater is the prevalence of lime felspar as contracted with soda or potash felspar. Clarke has calculated the relative abundance of the principal rock-forming minerals with the following results: Apatite = 0.6, titanium minerals = 1.5, quartz = 12.0, felspars = 59.5, biotite = 3.8, hornblende and pyroxene = 16.8, total = 94.2%. This, however, can only be a rough approximation. The other determining factor, namely the physical conditions attending consolidation, plays on the whole a smaller part, yet is by no means negligible, as a few instances will prove There are certain minerals which are practically confined to deep-seated intrusive rocks, e.g. microcline, muscovite, diallage. Leucite is very rare in plutonic masses; many minerals have special peculiarities in microscopic character according to whether they crystallized in depth or near the surface, e.g. hypersthene, orthoclase, quartz. There are some curious instances of rocks having the same chemical composition but consisting of entirely different minerals, e.g. the hornblendite of Gran, in Norway, containing only hornblende, has the same composition as some of the camptonites of the same locality which contain felspar and hornblende of a different variety. In this connexion we may repeat what has been said above about the corrosion of porphyritic minerals in igneous rocks. In rhyolites and trachytes early crystals of hornblende and biotite may be found in great numbers partially converted into augite and magnetite. The hornblende and biotite were stable under the pressures and other conditions which obtained below the surface, but unstable at higher levels. In the ground-mass of these rocks augite is almost universally present. But the plutonic representatives of the same magma, granite and syenite contain biotite and hornblende far more commonly than augite.
Those rocks which contain most silica and on crystallizing yield free quartz are erected into a group generally designated the “acid” rocks. Those again which contain least silica and most magnesia and iron, so that quartz is absent while olivine is usually abundant, form the Acid, Intermediate and Basic Igneous Rocks.“basic” group. The “intermediate” rocks include those which are characterized by the general absence of both quartz and olivine An important subdivision of these contains a very high percentage of alkalis, especially soda, and consequently has minerals such as nepheline and leucite not common in other rocks. It is often separated from the others as the “alkali” or “soda” rocks, and there is a corresponding series of basic rocks. Lastly a small sub-group rich in olivine and without felspar has been called the “ultra basic” rocks. They have very low percentages of silica but much iron and magnesia.
Except these last practically all rocks contain felspars or felspathoid minerals. In the acid rocks the common felspars are orthoclase, with perthite, microcline, oligoclase, all having much silica and alkalis. In the basic rocks labradorite, anorthite and bytownite prevail, being rich in lime and poor in silica, potash and soda. Augite is the commonest ferro-magnesian of the basic rocks, but biotite and hornblende are on the whole more frequent in the acid.
| Commonest Minerals. | Acid. | Intermediate. | Basic. | Ultrabasic. | |
| Quartz Orthoclase (and Oligo- clase), Mica, Hornblende, Augite. | Little or no Quartz. | No Quartz Plagioclase Augite, Olivine. | No Felspar Augite, Hornblende, Olivine. | ||
| Orthoclase Hornblende, Augite, Biotite. | Plagioclase Hornblende, Augite, Biotite. | ||||
| Plutonic or Abyssal type. | Granite. | Syenite. | Diorite. | Gabbro. | Peridotite. |
| Intrusive or Hypabyssal type. | Quartz- porphyry. | Orthoclase- porphyry. | Porphyrite. | Dolerite. | Picrite. |
| Lavas or Effusive type. | Rhyolite, Obsidian. | Trachyte. | Andesite. | Basalt. | Limburgite. |
The rocks which contain leucite or nepheline, either partly or wholly replacing felspar are not included in this table. They are essentially of intermediate or of basic character. We might in consequence regard them as varieties of syenite diorite, gabbro, &c. in which felspathoid minerals occur, and indeed there are many transitions between syenites of ordinary type and nepheline—or leucite—syenite, and between gabbro or dolerite and theralite or essexite. But as many minerals develop in these “alkali” rocks which are uncommon elsewhere, it is convenient in a purely formal classification like that which is outlined here to treat the whole assemblage as a distinct series.
Nepheline and Leucite-bearing Rocks.
| Commonest Minerals. | Alkali Felspar, Nepheline or Leu- cite, Augite, Horn- blende, Biotite. | Soda Lime Felspar Nepheline or Leu- cite,Augite,Horn- blende (Olivine). | Nepheline or Leucite, Augite, Hornblende, Olivine. |
| Plutonic type. | Nepheline-syenite. Leucite-syenite. | Essexite and Theralite. | Ijolite and Missourite. |
| Intrusive type. | Nepheline-porphyry | ||
| Effusive type or Lavas. | Phonolite, Leucitophyre. | Tephrite and Basanite. | Nepheline- basalt. Leucite-basalt |
This classification is based essentially on the mineralogical constitution of the igneous rocks. Any chemical distinctions between the different groups, though implied, are relegated to a subordinate position. It is admittedly artificial but it has grown up with the growth of the science and is still adopted as the basis on which more minute subdivisions are erected. The subdivisions are by no means of equal value. The syenites, for example, and the peridotites, are far less important than the granites, diorites and gabbros. Moreover, the effusive andesites do not always correspond to the plutonic diorites but partly also to the gabbros. As the different kinds of rock, regarded as aggregates o minerals, pass gradually into one another, transitional types are very common and are often so important as to receive special names. The quartz-syenites and nordmarkites may be interposed between granite and syenite, the tonalities and adamellites between granite and diorite, the monzonites between syenite and diorite, norites and hyperites between diorite and gabbro, and so on.
There is of course a large number of recognized rock species not included in the tables given. These are of two kinds, either belonging to groups which are subdivisions of those enumerated (bearing the same relation to them that species do to genera) or rare and exceptional rocks that do not fall within any of the main subdivisions proposed. The question may be asked—When is a rock entitled to be recognized as belonging to a distinct species or variety and deserving a name for itself? It must, first of all, be proved to occur in considerable quantity at some locality, or better still at a series of localities or to have been produced from different magmas at more than one period of the earth’s history In other words, it must not be a mere anomaly. Moreover, it should have a distinctive mineral constitution, differing from other rocks, or something individual in the characters of its minerals or of its structures. It is often surprising how peculiar types of rock, believed at first
