CHAPTER XIII.
EFFECT OF VARIOUS PROCESSES ON AN ENSEMBLE OF SYSTEMS.
In the last chapter and in Chapter I we have considered the changes which take place in the course of time in an ensemble of isolated systems. Let us now proceed to consider the changes which will take place in an ensemble of systems under external influences. These external influences will be of two kinds, the variation of the coördinates which we have called external, and the action of other ensembles of systems. The essential difference of the two kinds of influence consists in this, that the bodies to which the external coördinates relate are not distributed in phase, while in the case of interaction of the systems of two ensembles, we have to regard the fact that both are distributed in phase. To find the effect produced on the ensemble with which we are principally concerned, we have therefore to consider single values of what we have called external coördinates, but an infinity of values of the internal coördinates of any other ensemble with which there is interaction.
Or,—to regard the subject from another point of view,—the action between an unspecified system of an ensemble and the bodies represented by the external coördinates, is the action between a system imperfectly determined with respect to phase and one which is perfectly determined; while the interaction between two unspecified systems belonging to different ensembles is the action between two systems both of which are imperfectly determined with respect to phase.[1]
We shall suppose the ensembles which we consider to be distributed in phase in the manner described in Chapter I, and- ↑ In the development of the subject, we shall find that this distinction corresponds to the distinction in thermodynamics between mechanical and thermal action.
